Impact of ligands and media on the structure and properties of biological and biomimetic iron-sulfur clusters

Ohta Shun; Ohki Yasuhiro

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Impact of ligands and media on the structure and properties of biological and biomimetic iron-sulfur clusters

机译：配体和介质对生物仿生铁硫团簇结构和性能的影响

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Iron-sulfur clusters are inorganic centers that are widely distributed in nature, mediating electrontransfer processes and transformation reactions. Their properties and functions arise from the different amino acid residues on the iron centers, some weak interactions within the protein matrices, and the extent of exposure to the medium. Studies on biomimetic model clusters have elucidated the molecular basis of the effects of iron-bound ligands and solvents on the synthesis and properties of iron-sulfur clusters. This review summarizes the effects of ligands and media on the properties and structure of both biological and biomimetic iron-sulfur clusters. (C) 2017 Elsevier B.V. All rights reserved.

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来源
《Coordination chemistry reviews》 |2017年第5期|207-225|共19页
作者
Ohta Shun; Ohki Yasuhiro;
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作者单位

Hirosaki Univ, Graduate Sch Sci & Technol, Dept Forntier Mat Chem, Hirosaki, Aomori 0368561, Japan;

Nagoya Univ, Graduate Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan|Japan Sci & technol Agency, PRESTO, Kawaguchi, Saitama, Japan;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Iron; Sulfur; Cluster; Biomimetic; Model compound;

机译：铁;硫;簇;仿生;模型化合物;

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1. THE FUNCTION AND PROPERTIES OF THE IRON-SULFUR CENTER IN SPINACH FERREDOXIN-THIOREDOXIN REDUCTASE - A NEW BIOLOGICAL ROLE FOR IRON-SULFUR CLUSTERS [J] . Staples CR, Ameyibor E, Fu WG, Biochemistry . 1996,第35期

机译：铁硫化物-硫氧化还原酶菠菜中铁硫中心的功能和特性
2. Zinc-Ligand Swapping Mediated Complex Formation and Sulfur Transfer between SufS and SufU for Iron-Sulfur Cluster Biogenesis in Bacillus subtilis [J] . Takashi Fujishiro, Takuya Terahata, Kouhei Kunichika, Journal of the American Chemical Society . 2017,第51期

机译：锌-配体交换介导的复合物形成和SufS和SufU之间的硫转移，用于枯草芽孢杆菌中铁硫簇的生物发生。
3. Reaction of Mixed-Ligand Iron-Sulfur Cluster [Fe_4(Cp~*)_3(Ph_2C_2S_2)(mu_3-S)_3(mu_3-S_2)](Cp~*=C_5Me_5)with Methyl Iodide.Synthesis,Structure,and Redox Behavior of [Fe_4(Cp~*)_3(Ph_2C_2S_2)(mu_3-S)_3(mu_3-S_2Me)] [J] . Shinji Inomata, Keiichi Hitomi, Hiroshi Ogino Bulletin of the Chemical Society of Japan . 2004,第6期

机译：混合配体铁 - 硫簇的反应[Fe_4（cp〜*）_ 3（pH_2c_2s_2）（mu_3-s）_3（mu_3-s_2）]（cp〜* = 5me_5），具有甲基碘。合成，结构和氧化还原行为 [fe_4（cp〜*）_ 3（ph_2c_2s_2）（mu_3-s）_3（mu_3-s_2me）]
4. Effects of Crosslinking Condition on Mechanical and Biological Properties of Biomimetic Fibrous Composite Material for Arterial Medial Equivalent [C] . K. Madhavan, D. Belchenko, W. Tan Nanotechnology 2009 : Technical proceedings . 2009

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5. Investigation of the electronic structure of bioinorganic systems using ligand K-edge X-ray absorption spectroscopy: Application to copper(A), metal tetrathiolates and iron-sulfur clusters. [D] . Rose, Kendra Sue. 1999

机译：使用配体K边缘X射线吸收光谱研究生物无机系统的电子结构：在铜（A），金属四硫醇盐和铁硫簇中的应用。
6. Structural/Functional Properties of Human NFU1 an Intermediate 4Fe-4S Carrier in Human Mitochondrial Iron-Sulfur Cluster Biogenesis [O] . Kai Cai, Gaohua Liu, Ronnie O. Frederick, -1

机译：人NFU1人线粒体铁-硫簇生物发生的中间4Fe-4S载体的结构/功能特性。
7. Tetranuclear iron-sulfur cluster compounds: syntheses, structures, and redox properties [O] . Blonk H.L. 1991

机译：四核铁硫簇化合物：合成，结构和氧化还原性质
8. Tetranuclear Iron-Sulfur Cluster Compounds: Syntheses, Structures, and Redox Properties [R] . Blonk, H. L. 1993

机译：四核铁硫簇化合物：合成，结构和氧化还原性质

Impact of ligands and media on the structure and properties of biological and biomimetic iron-sulfur clusters

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