Re-I(CO)(3) complexes with diimine ligands synthesized in situ

Villafane Fernando

首页> 外文期刊>Coordination chemistry reviews >Re-I(CO)(3) complexes with diimine ligands synthesized in situ

【24h】

Re-I(CO)(3) complexes with diimine ligands synthesized in situ

机译：Re-I（CO）（3）配合物与二亚胺配体原位合成

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

This work covers the coupling reactions of monodentate ligands coordinated to the "Re-I(CO)(3)" moiety to afford in situ new bidentate diimine ligands.Similar reactions leading to tridentate ligands are also included.The reactions reviewed present evident advantages respect to the usual synthetic methods of these ligands.Besides, choosing the appropriate substituents allows an easy tuning of the properties of the final complexes.Following an approximate chronological order, the formation of bidentate ligands by C-N coupling from a coordinated carbonyl group, from diiminoisoindoline, and the formation of amidino ligands from nitriles are reviewed first.This is followed by the formation of bidentate ligands by C-C coupling, and finally by the formation of tridentate ligands, either by C-C coupling, by B-N coupling, or by using "click" reactions. (C) 2017 Elsevier B.V.All rights reserved.

机译：这项工作涵盖了与“ Re-I（CO）（3）”部分配位的单齿配体的偶联反应，以提供原位新的双齿二亚胺配体。还包括导致三齿配体的类似反应。这些配体的常规合成方法。此外，选择合适的取代基还可以轻松调节最终配合物的性能。按照近似的时间顺序，由配位羰基，二亚氨基异吲哚啉，CN，首先审查由腈形成的nitr基配体。其次是通过CC偶联形成二齿配体，最后通过CC偶联，BN偶联或通过“点击”反应形成三齿配体。。（C）2017 Elsevier B.V.保留所有权利。

著录项

来源
《Coordination chemistry reviews》 |2017年第5期|128-137|共10页
作者
Villafane Fernando;
展开▼
作者单位

Univ Valladolid, Fac Ciencias, GIR MIOMeT IU Cinquima, Quim Inorgan, Campus Miguel Delibes, E-47011 Valladolid, Spain;

展开▼
收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Coupling reactions; Diimines; In situ synthesis; Rhenium; Tridentate ligands;

机译：偶联反应;二亚胺;原位合成;R;状配体;

相似文献

外文文献
中文文献
专利

1. Influence of a Naphthaldiimide Substituent at the Diimine Ligand on the Photophysics and Reverse Saturable Absorption of Pt-II Diimine Complexes and Cationic Ir-III Complexes [J] . Liu Rui, Dandu Naveen, McCleese Christopher, European journal of inorganic chemistry . 2015,第31期

机译：Diimine配体上的萘二酰亚胺替代物对Pt-II Diimine配合物和阳离子Ir-III配合物的光物理性质和反向饱和吸收的影响
2. VOLTAMMETRY OF MONOMERIC AND DIMERIC OXORHENIUM(V) COMPLEXES OF SCHIFF BASE LIGANDS N,N'-ETHYLENEBIS(ACETYLACETONE)DIIMINE, N,N'-ETHYLENE(SALICYLIDENE)DIIMINE AND N,N'-PHENYLENEBIS(SALICYLIDENE)DIIMINE [J] . Bottomley LA., Holder GN., Wojciechowski PE. Inorganica Chimica Acta . 1997,第1期

机译：席夫夫碱配体N，N'-乙烯（乙炔）二亚胺，N，N'-乙烯（水杨基）二亚胺和N，N'-苯基（水杨基）二亚胺的单价和二价氧化HEN（V）络合物的伏安法
3. INSERTION REACTIONS INVOLVING PALLADIUM COMPLEXES WITH NITROGEN LIGANDS .1. REACTIVITY TOWARDS CARBON MONOXIDE OF METHYLPALLADIUM(II) COMPLEXES CONTAINING BIDENTATE ALPHA-DIIMINE LIGANDS - CRYSTAL STRUCTURES OF FOUR METHYLPALLADIUM(II) AND ACYLPALLAD [J] . Rulke RE., Groot AM., Elsevier CJ., Journal of Organometallic Chemistry . 1996,第1a2期

机译：含钯配位化合物与氮配体的插入反应1。包含二齿二甲双二胺配体的甲基钯（II）配合物对一氧化碳的反应性-四个甲基钯（II）和紫杉醇的晶体结构
4. Dependence of Stability of the Polymerizesd Nickel Complexes with Schiff Bases on the Structure of the Ligand Diimine Bridge [C] . E. V. Alekseeva, V. A. Ershov, A. S. Konev, International Conference on Advanced Batteries, Accumulators and Fuel Cells . 2018

机译：聚合镍复合物与席夫碱对配体二亚胺桥结构的依赖性依赖性
5. Elucidating photophysical attributes of alpha,alpha'-diimine ligands, rhodium(III) dicyano-bis (alpha,alpha'-diimine) and tris(alpha,alpha'-diimine) complexes via ab inition and density-functional calculations. [D] . Matz, Phillip Daniel. 2002

机译：阐明了α，α'-二亚胺配体，铑（III）二氰基双（α，α'-二亚胺）和三（α，α'-二亚胺）配合物的光物理属性，方法是通过原子和密度函数计算。
6. Square-Planar Heteroleptic Complexes of α-Diimine-NiII-Catecholate Type: Intramolecular Ligand-to-Ligand Charge Transfer [O] . Kira I. Pashanova, Vladlena O. Bitkina, Ilya A. Yakushev, 2021

机译：α-二亚胺-NIII-CateCholate型的方形平面杂化复合物：分子内配体 - 配体电荷转移
7. Re I (CO) 3 complexes with diimine ligands synthesized in situ [O] . Fernando Villafañe 2017

机译：Re（CO）3与原位合成的二氨基配体的复合物
8. Ligand Oxidation in Iron Diimine Complexes. 3. Electrochemical Oxidation of Tris(glyoxal bis(methylimine)) iron(II). [R] . Chum, H. L., Rabockai, T., Phillips, J., 1976

机译：铁二亚胺配合物中的配体氧化。 3.三（乙二醛双（甲基亚胺））铁（II）的电化学氧化。

Re-I(CO)(3) complexes with diimine ligands synthesized in situ

摘要

著录项

相似文献

相关主题

期刊订阅