Recent advances in the coordination chemistry of cerium(IV) complexes

So Yat-Ming; Leung Wa-Hung

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Recent advances in the coordination chemistry of cerium(IV) complexes

机译：铈（IV）配合物配位化学的最新进展

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Despite widespread applications of tetravalent cerium compounds in organic synthesis and catalysis, the coordination and organometallic chemistry of cerium(IV) complexes has not been well explored, due, in part, to the high oxidizing power of Ce(IV). Using chelating O-donor supporting ligands, stable tetravalent cerium complexes bearing various ligand functionalities have been isolated, thus making it possible to investigate the reaction chemistry of cerium(IV) complexes systematically. This review summarizes the recent developments of the coordination chemistry of cerium(IV) complexes bearing O-, N-, and C-donor ligands. Special attention will be directed to cerium(IV) complexes supported by a tripodal oxygen ligand. (C) 2016 Elsevier B.V. All rights reserved.

机译：尽管四价铈化合物在有机合成和催化中得到广泛应用，但由于部分原因是Ce（IV）的高氧化能力，铈（IV）配合物的配位和有机金属化学尚未得到很好的研究。使用螯合的O-供体支持配体，已分离出具有各种配体功能的稳定的四价铈配合物，从而使系统研究铈（IV）配合物的反应化学成为可能。这篇综述总结了带有O-，N-和C-供体配体的铈（IV）配合物配位化学的最新进展。将特别注意由三脚架氧配体支持的铈（IV）配合物。（C）2016 Elsevier B.V.保留所有权利。

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《Coordination chemistry reviews》 |2017年第6期|172-197|共26页
作者
So Yat-Ming; Leung Wa-Hung;
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作者单位

Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China;

Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Cerium; Tetravalent complexes; O-donor ligands;

机译：铈;四价配合物;O-供体配体;

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1. Bond valence sums in coordination chemistry. The calculation of the oxidation state of cerium in complexes containing cerium bonded only to oxygen [J] . Roulhac PL., Palenik GJ. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第1期

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2. Cerium(III/IV) and Cerium(IV)-Titanium(IV) Citric Complexes Prepared in Ethylene Glycol Medium [J] . M. Getsova, D. Todorovsky, V. Enchev Monatshefte fur Chemie . 2007,第5期

机译：乙二醇介质中制备的铈（III / IV）和铈（IV）-钛（IV）柠檬酸络合物
3. Cationic cerium(IV) complexes with multiple open coordination sites [J] . Lukman A. Solola, Patrick J. Carroll, Eric J. Schelter Journal of Organometallic Chemistry . 2018,第期

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4. In Vivo Coordination Chemistry and Biolocalization of Bis(ligand)oxovanadium(IV) Complexes for Diabetes Treatment [C] . Katherine H. Thompson, Barry D. Liboiron, Graeme R. Hanson, Symposium on Medicinal Inorganic Chemistry . 2005

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5. Synthesis and crystallography of cerium(IV) bis porphyrinates and hafnium(IV) mono porphyrinates; a tool box for supramolecular chemistry . [D] . Falber, Alexander. 2007

机译：双卟啉铈（IV）和单卟啉ha（IV）的合成和晶体学；超分子化学工具箱。
6. From the Cover: Coordination Chemistry of Saturated Molecules Special Feature: Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules [O] . Gregory J. Kubas 2007

机译：从封面开始：饱和分子的配位化学特殊功能：二氢配合物作为饱和分子配位化学的原型
7. Schiff Base Cerium (IV) Complexes possibly with Eight-coordination [O] . Shoichiro Yamada, Akira Takeuchi, Hiroki Yamakita 1967

机译：Schiff基铈（IV）配合物可能有八个协调

Recent advances in the coordination chemistry of cerium(IV) complexes

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