Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru

Humphries Terry D.; Sheppard Drew A.; Buckley Craig E.

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Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru

机译：Ni，Fe，Co和Ru的18电子复合过渡金属氢化物的最新研究进展

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Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional applications; including, smart optical windows, energy storage materials in fuel cells for both stationary and mobile devices, and as thermal energy storage materials for concentrating solar thermal plants. This review concentrates on the molecular structures, thermodynamic properties and other physical properties of the complexes of [NiH4](4), [FeH6](4), [CoH5](4) and [RuH6](4). The synthesized derivatives of these compounds have also been reviewed to give a full overview on the advancement of these systems and will allow for a fresh prospective for future studies to fully understand the physical and chemical nature of these complex transition metal hydrides. (C) 2017 Elsevier B.V. All rights reserved.

机译：由于氢经济的蓬勃发展，金属氢化物备受关注。此外，最近对金属氢化物材料的研究表明，这些化合物的技术实施不仅在于氢的存储，而且还涉及一系列的多功能应用。包括智能光学窗，用于固定和移动设备的燃料电池中的能量存储材料，以及用于集中太阳能热电厂的热能存储材料。这篇综述集中于[NiH4]（4），[FeH6]（4），[CoH5]（4）和[RuH6]（4）配合物的分子结构，热力学性质和其他物理性质。还审查了这些化合物的合成衍生物，以全面概述这些系统的发展，并为将来的研究提供了新的前景，以充分了解这些复杂的过渡金属氢化物的物理和化学性质。（C）2017 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第7期|19-33|共15页
作者
Humphries Terry D.; Sheppard Drew A.; Buckley Craig E.;
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作者单位

Curtin Univ, Fuels & Energy Technol Inst, Dept Phys & Astron, GPO Box U1987, Perth, WA 6845, Australia;

Curtin Univ, Fuels & Energy Technol Inst, Dept Phys & Astron, GPO Box U1987, Perth, WA 6845, Australia;

Curtin Univ, Fuels & Energy Technol Inst, Dept Phys & Astron, GPO Box U1987, Perth, WA 6845, Australia;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Complex transition metal hydride; Thermodynamics; Structure; Hydrogen storage; Thermal energy storage; Review;

机译：复杂过渡金属氢化物;热力学;结构;储氢;热能存储;综述;

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1. Transition metal complexes with sulfur ligands. 130. Synthesis, structure, and reactivity of the sulfur-rich ruthenium hydride complexes [Ru(H)(PR3)('S-4')(-) and the eta(2)-H-2 complex [Ru(H-2)(PCy3)('S-4')] (R = Ph, Pr-i, Cy; 'S-4'(2-) = 1,2-bis((2 [J] . Sellmann D., Heinemann FW., Gottschalk-Gaudig T. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第16期

机译：具有硫配体的过渡金属配合物。 130.富硫氢化钌络合物[Ru（H）（PR3）（'S-4'）（-）和eta（2）-H-2络合物[Ru（H- 2）（PCy3）（'S-4'）]（R = Ph，Pr-i，Cy;'S-4'（2-）= 1,2-bis（（2
2. ANODICALLY-INDUCED METAL DEPROTONATION OF THE HYDRIDE COMPLEXES [(PCH2CH2PPH2)(3))M(H)CL] (M=FE, RU, OS) - THE FIRST STEP TO THE ELECTROGENERATION OF FE(I), RU(I) AND OS(I) FIVE-COORDINATE COMPLEXES [J] . Bianchini C., Ceccanti A., Laschi F., Inorganica Chimica Acta . 1997,第1a2期

机译：氢化物[[PCH2CH2PPH2）（3））M（H）CL的阳极诱导金属质子化（M = FE，RU，OS）-电化FE（I），RU（I）和OS（I）五坐标复合体
3. Activation and Cleavage of H-R Bonds through Intermolecular H-H Bonding upon Reaction of Proton Donors HR with 18-Electron Transition Metal Hydrides [J] . Galina Orlova, Steve Scheiner, Tapas Kar The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1999,第4期

机译：质子供体HR与18电子过渡金属氢化物反应后，通过分子间H-H键活化和裂解H-R键
4. Density Functional Theory Study of the Effect of 3d and 4d Transition Metals on NaMgH3 Complex Metal Hydride for Hydrogen Storage Applications [C] . Fernando Soto, Daniela S. Mainardi AIChE annual meeting . 2011

机译：储氢应用中3d和4d过渡金属对NaMgH3复合金属氢化物的影响的密度泛函理论研究
5. First-principles point defect models in Zr7Ni10 and Zr2Ni7 binary intermetallic compounds and their implications in nickel-metal hydride batteries. [D] . Wong, Diana F. 2015

机译：Zr7Ni10和Zr2Ni7二元金属间化合物的第一性原理点缺陷模型及其在镍氢电池中的意义。
6. Varied roles of Pb in transition-metal PbMO3 perovskites (M = Ti V Cr Mn Fe Ni Ru) [O] . John B Goodenough, Jianshi Zhou 2015

机译：Pb在过渡金属PbMO3钙钛矿中的各种作用（M = TiVCrMnFeNiRu）
7. Thermochromic organometallic complexes: experimental and theoretical studies of 16- to 18-electron interconversions of adducts of arene Ru(ii) carboranes with aromatic amine ligands [O] . Nicolas P. E. Barry, Robert J. Deeth, Guy J. Clarkson, 2013

机译：热致变色器有机金属配合物：具有芳香胺配体的芳烃（II）羰烷加合物的16至18〜18〜18〜18〜18电互联的实验性和理论研究

Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru

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