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首页> 外文期刊>Coordination chemistry reviews >Lewis acid catalysis on single site Sn centers incorporated into silica hosts
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Lewis acid catalysis on single site Sn centers incorporated into silica hosts

机译：路易斯酸在掺入二氧化硅主体中的单中心锡中心催化

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摘要

Tetrahedral Sn built into microporous silica frameworks such as zeolites and structured mesoporous silica can be used as heterogeneous Lewis acid catalysts. These materials have recently attracted much attention, as they show remarkable activity and selectivity in a wide range of reactions. A prominent example is the conversion of carbohydrates into platform and commodity chemicals such as lactic acid or alkyl lactates, where the activity and selectivity of Sn-based materials remains unsurpassed compared to Sn-free catalysts. Some of the-materials show water-tolerant behavior and can therefore also be used in aqueous systems. In this work, a literature overview regarding synthesis of Sn-containing silica materials is given, as well as a synopsis of the characterization tools which can be used to unravel the structure of the catalytic active site. The application of such Sn-containing materials for diverse catalytic reactions is reviewed, with special emphasis on the effects of the catalyst characteristics on the catalytic activity and stability. (C) 2017 Elsevier B.V. All rights reserved.
机译：内置于微孔二氧化硅骨架（例如沸石）和结构化中孔二氧化硅中的四面体Sn可用作多相路易斯酸催化剂。这些材料最近引起了广泛的关注，因为它们在各种反应中均显示出卓越的活性和选择性。一个突出的例子是碳水化合物向平台和日用化学品（如乳酸或乳酸烷基酯）的转化，与不含锡的催化剂相比，基于锡的材料的活性和选择性仍然无法超越。一些材料表现出耐水性能，因此也可用于水性体系。在这项工作中，给出了有关含锡二氧化硅材料合成的文献综述，以及概述可用于解开催化活性位点结构的表征工具的概述。综述了这种含锡材料在各种催化反应中的应用，特别强调了催化剂特性对催化活性和稳定性的影响。 （C）2017 Elsevier B.V.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2017年第7期|220-255|共36页
  • 作者

    Ferrini Paola; Dijkmans Jan; De Clercq Rik; Van de Vyver Stijn; Dusselier Michiel; Jacobs Pierre A.; Sels Bert F.;

  • 作者单位

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

    Katholieke Univ Leuven, Ctr Surface Sci & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Sn beta; Zeolite; Lewis acid; Biomass; Stannosilicates;

    机译：锡β;沸石;路易斯酸;生物质;锡硅酸盐;

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