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Recent advances in the construction and applications of heterometallic macrocycles and cages

机译：杂金属大环和笼的建设和应用的最新进展

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摘要

Discrete supramolecular constructs continue to attract strong research interest because of their myriad applications. Most of the work in this area has been performed with a single type of metal atom or ion and one or two organic ligands, but considerable success has also been achieved by employing heterometallic systems. The focus of this review is on recent developments in the area of discrete heterometallic architectures. The two main synthetic strategies towards these metallamacrocycles and metallacages are discussed, and special attention is given to molecular structures with special shapes and functions, such as catalysts, host-guest properties and others. (C) 2016 Elsevier B.V. All rights reserved.
机译：离散的超分子构建体由于其无数的应用而继续引起强烈的研究兴趣。该领域的大多数工作是用单一类型的金属原子或离子和一个或两个有机配体完成的，但是通过采用异金属系统也取得了相当大的成功。本文的重点是离散异金属结构领域的最新发展。讨论了针对这些金属lamcrocrocycles和metallacages的两种主要合成策略，并特别注意具有特殊形状和功能的分子结构，例如催化剂，客体性质等。 （C）2016 Elsevier B.V.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2017年第8期|323-344|共22页
  • 作者

    Zhang Ying-Ying; Gao Wen-Xi; Lin Lin; Jin Guo-Xin;

  • 作者单位

    Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China|Zhongyuan Univ Technol, Ctr Adv Mat Res, Zhengzhou 451191, Peoples R China;

    Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China;

    Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China;

    Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Heterometallic macrocycles/cages; Metalloligand; Self-sorting; Host-guest chemistry; Catalyst;

    机译：杂金属大环/笼;金属配体;自选;主客体化学;催化剂;

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