Benzoquinonediimine ligands: Synthesis, coordination chemistry and properties

Pascal Simon; Siri Olivier

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Benzoquinonediimine ligands: Synthesis, coordination chemistry and properties

机译：苯并醌二亚胺配体：合成，配位化学和性质

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This review covers the synthesis and properties of 2,5-diamino-1,4-benzoquinonediimines (DABQDI), and their use as ligand in coordination chemistry. Although reported more than a century ago, these molecules emerged as highly versatile ligands only from 1998, and are so far used for the synthesis of numerous complexes with remarkable properties. This exceptional versatility results from the possible tuning of the N-substituents and the observation of an isomerization process upon coordination depending on the metal center. As such, these DABQDI can be also considered as ligands that combine the structural elements of ortho- and para-benzoquinonediimines (o-BQDI and p-BQDI) which are bidentate monotopic and monodentate ditopic ligands, respectively. These two classes of BQDI ligands are also reviewed in order to parallel their properties to those of the complexes based on DABQDI. (C) 2017 Elsevier B.V. All rights reserved.

机译：这篇综述涵盖了2,5-二氨基-1,4-苯并醌二亚胺（DABQDI）的合成和性质，以及它们在配位化学中作为配体的用途。尽管已有一个多世纪的报道，但这些分子直到1998年才以高度通用的配体形式出现，迄今为止已用于合成许多具有显着特性的复合物。这种非凡的多功能性来自于N取代基的可能调节，以及根据金属中心进行配位观察的异构化过程。这样，这些DABQDI也可以被认为是结合了分别为双齿单位和单齿双位配体的邻-和对-苯并醌二亚胺（o-BQDI和p-BQDI）的结构元素的配体。还对这两类BQDI配体进行了综述，以使其性质与基于DABQDI的复合物的性质平行。（C）2017 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第11期|178-195|共18页
作者
Pascal Simon; Siri Olivier;
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作者单位

Aix Marseille Univ, CNRS, UMR 7325, CINaM, Campus Luminy,Case 913, F-13288 Marseille 09, France;

Aix Marseille Univ, CNRS, UMR 7325, CINaM, Campus Luminy,Case 913, F-13288 Marseille 09, France;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Mononuclear complexes; Dinuclear complexes; Polynuclear complexes; Absorption spectroscopy; Metal-metal interaction; Ligand synthesis; Redox properties; lsomerization; Benzoquinonediimine;

机译：单核配合物;双核配合物;多核配合物;吸收光谱;金属-金属相互作用;配体合成;氧化还原性质;异构化;苯醌二亚胺;

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Benzoquinonediimine ligands: Synthesis, coordination chemistry and properties

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