Surface chemistry of carboxylato-substituted metal oxo clusters - Model systems for nanoparticles

Schubert Ulrich

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Surface chemistry of carboxylato-substituted metal oxo clusters - Model systems for nanoparticles

机译：羧基取代的金属氧基团簇的表面化学-纳米颗粒的模型系统

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Clusters can be model systems for nanoparticles with regard to the chemistry of surface groups. Metal oxo clusters with carboxylato ligands are easily accessible and therefore well-suited for investigating the chemistry of cluster-bonded ligands. This review article gives an account on issues like ligand dynamics, post-synthesis ligand exchange, stability of the cluster core during ligand exchange, possible mechanisms of intra- and intermolecular ligand exchange or utilizing functional ligands. (C) 2017 The Author(s). Published by Elsevier B.V.

机译：关于表面基团的化学性质，簇可以是纳米颗粒的模型系统。带有羧基配体的金属羰基簇很容易获得，因此非常适合用于研究簇键合配体的化学性质。这篇综述文章阐述了配体动力学，合成后配体交换，配体交换过程中簇核心的稳定性，分子内和分子间配体交换或利用功能性配体的可能机理等问题。（C）2017作者。由Elsevier B.V.发布

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来源
《Coordination chemistry reviews》 |2017年第11期|61-67|共7页
作者
Schubert Ulrich;
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作者单位

Vienna Univ Technol, Inst Mat Chem, Getreidemarkt 9, A-1060 Vienna, Austria;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Ligand dynamics; Cluster rearrangement; Cluster degradation; Ligand exchange; Surface functionalization; Nanostructures;

机译：配体动力学;簇重排;簇降解;配体交换;表面功能化;纳米结构;

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专利

1. Retention of the Cluster Core Structure during Ligand Exchange Reactions of Carboxylato-Substituted Metal Oxo Clusters [J] . Kreutzer Johannes, Puchberger Michael, Artner Christine, European journal of inorganic chemistry . 2015,第12期

机译：羧基取代的金属氧簇的配体交换反应中簇核心结构的保留
2. Hydrolysis of organometallic and metal-amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles [J] . Garden J. A., Pike S. D. Dalton transactions: An international journal of inorganic chemistry . 2018,第11期

机译：有机金属和金属 - 酰胺前体的水解：合成氧化桥杂核络合物，金属 - 氧簇和金属氧化物纳米粒子
3. Metal Reactivity on Oxo Surfaces Modeled by Calix [4]arenes:Metal-Driven Reactions in an Oxo-Quasiplanar Environment [J] . Floriani Carlo Chemistry: A European journal . 1999,第1期

机译：用杯[4]芳烃模拟在氧表面上的金属反应性：在氧准平面环境中的金属驱动反应
4. Surface Chemistry of Metal Oxide Nanoparticles and Attachment of Metal Nanoclusters: Sensor, Optoelectronic and Photocatalytic Applications [C] . James E. Whitten National SBIR/STTR conference;Annual nanotech conference and expo;Annual TechConnect world innovation conference expo . 2015

机译：金属氧化物纳米粒子的表面化学和金属纳米团簇的附着：传感器，光电和光催化应用
5. New developments and applications in quantum chemistry: Fragment-based models for large molecular systems and structure-reactivity relationship of small transition metal chalcogenide clusters [D] . Saha, Arjun. 2016

机译：量子化学的新进展和应用：基于片段的大型分子系统模型和小型过渡金属硫族化物簇的结构反应性关系
6. Retention of the Cluster Core Structure during Ligand Exchange Reactions of Carboxylato-Substituted Metal Oxo Clusters [O] . Johannes Kreutzer, Michael Puchberger, Christine Artner, -1

机译：羧基取代的金属氧簇的配体交换反应中簇核心结构的保留
7. Retention of the Cluster Core Structure during Ligand Exchange Reactions of Carboxylato-Substituted Metal Oxo Clusters [O] . Johannes Kreutzer, Michael Puchberger, Christine Artner, 2015

机译：在羧酸盐替换金属氧代群的配体交换反应过程中保持簇芯结构

Surface chemistry of carboxylato-substituted metal oxo clusters - Model systems for nanoparticles

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