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Metal-radical coordination complexes of thiazyl and selenazyl ligands

机译:噻唑基和硒氮基配体的金属自由基配位化合物

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The so-called "metal-radical approach" to the design of molecule-based magnetic materials relies on the availability of paramagnetic ligands that can reliably form coordination complexes with paramagnetic metal ions. While the most common radical ligands are based on nitroxides, other paramagnetic building blocks are also gaining attention. Thiazyls and their related selenazyls are promising candidates for the development of radical ligands and, because they have inherently interesting materials' properties, their use as ligands has the potential to generate novel materials with unprecedented properties. Significant progress has been made in this field in the past ten years. This review is a timely look back at the development of the field, highlighting the diversity of complexes and designs, and a look forward to a promising future. (C) 2014 Elsevier B.V. All rights reserved.
机译:设计基于分子的磁性材料的所谓“金属自由基方法”依赖于顺磁性配体的可用性,该顺磁性配体可以可靠地与顺磁性金属离子形成配位络合物。尽管最常见的自由基配体基于氮氧化物,但其他顺磁性构件也受到关注。噻唑及其相关的硒代氮烯是开发自由基配体的有前途的候选者,并且由于它们具有固有的有趣的材料特性,因此其用作配体的潜力有可能产生具有前所未有性能的新型材料。在过去的十年中,该领域已经取得了重大进展。这篇评论是对领域发展的及时回顾,强调了复合物和设计的多样性,并期待有希望的未来。 (C)2014 Elsevier B.V.保留所有权利。

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