Ruthenium and osmium complexes containing 2-(aminomethyl)pyridinen   (Ampy)-based ligands in catalysis

Chelucci Giorgio; Baldino Salvatore; Baratta Walter

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Ruthenium and osmium complexes containing 2-(aminomethyl)pyridinen (Ampy)-based ligands in catalysis

机译：含2-（氨基甲基）吡啶基（Ampy）配体的钌和配合物

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This account focuses on the application in catalysis of ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands. The combination of these aminoalkylpyridine ligands with appropriate phosphines affords ruthenium and osmium systems displaying unprecedented high catalytic activity and productivity in a variety of organic transformations such as hydrogenation by hydrogen transfer and dihydrogen, dehydrogenation, racemization, and alkylation. (C) 2015 Elsevier B.V. All

机译：该文献侧重于包含基于2-（氨基甲基）吡啶（Ampy）的配体的钌和络合物的催化应用。这些氨基烷基吡啶配体与适当的膦结合使用可提供钌和体系，在各种有机转化（例如通过氢转移和二氢加氢，脱氢，外消旋和烷基化）中表现出空前的高催化活性和生产率。（C）2015 Elsevier B.V.全部

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来源
《Coordination chemistry reviews》 |2015年第9期|29-85|共57页
作者
Chelucci Giorgio; Baldino Salvatore; Baratta Walter;
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作者单位

Univ Sassari, Dipartimento Agr, I-07100 Sassari, Italy.;

Univ Udine, Dipartimento Chim Fis Ambiente, I-33100 Udine, Italy.;

Univ Udine, Dipartimento Chim Fis Ambiente, I-33100 Udine, Italy.;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Ruthenium complexes; Osmium complexes; Aminoalkylpyridines; Transfer hydrogenation; Hydrogenation; Catalysis; Asymmetric catalysis;

机译：钌配合物complex配合物氨基烷基吡啶转移氢化加氢催化不对称催化;

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2. Reactivity of 2-(Diphenylphosphanyl)thiophenol (HSC_6H_4PPh_2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC_6H_4PPh_2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster [J] . Javier A. Cabezza, M. Angeles Martinez-Garcia, Victor Riera, European journal of inorganic chemistry . 2000,第3期

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4. "Bioinspired" Metal Complexes of Macrocyclic N_4~(2-) and Open Chain N_2O_2~(2-) Schiff base Ligands - a Link between Porphyrins and Salicylaldimines [C] . Ernst-G. Jager German-Italian Meeting of Coimbra Group Universities . 2000

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8. pH-Induced Intramolecular Quenching. Ligand-Bridged Complexes Containing Osmium and Ruthenium [R] . Loeb, B., Neyhart, G. A., Worl, L. A., 1989

机译：pH诱导的分子内猝灭。含有锇和钌的配体桥联配合物

Ruthenium and osmium complexes containing 2-(aminomethyl)pyridinen (Ampy)-based ligands in catalysis

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