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PEG as an alternative reaction medium in metal-mediated transformations

机译:PEG作为金属介导转化中的替代反应介质

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摘要

Poly(ethylene glycol)s (PEGs) are an interesting environment-friendly alternative to classical solvents. Their combination with metals and metallic salts provides powerful reaction systems for a wide variety of transformations. This study presents an overview of the various reactions developed in PEG together with a metallic species. The influence of PEG on the reaction course, the stabilizing effects of the polymer on the metals and the recycling possibility are reported for the various metallic elements of the periodic table.
机译:聚乙二醇(PEG)是传统溶剂的一种有趣的环保替代品。它们与金属和金属盐的结合为各种转化提供了强大的反应系统。这项研究概述了PEG中与金属物质一起发生的各种反应。对于元素周期表的各种金属元素,报道了PEG对反应过程的影响,聚合物对金属的稳定作用和再循环的可能性。

著录项

  • 来源
    《Coordination chemistry reviews》 |2012年第24期|2893-2920|共28页
  • 作者单位

    Institutdes Biomolecules Max Mousseron, UMR 5247 - Universite Montpellier 1 et Universite Montpellier 2-CNRS, Place Eugene Bataillon, 34095 Montpellier Cedex 05, France;

    Institutdes Biomolecules Max Mousseron, UMR 5247 - Universite Montpellier 1 et Universite Montpellier 2-CNRS, Place Eugene Bataillon, 34095 Montpellier Cedex 05, France;

    Institutdes Biomolecules Max Mousseron, UMR 5247 - Universite Montpellier 1 et Universite Montpellier 2-CNRS, Place Eugene Bataillon, 34095 Montpellier Cedex 05, France;

    Institutdes Biomolecules Max Mousseron, UMR 5247 - Universite Montpellier 1 et Universite Montpellier 2-CNRS, Place Eugene Bataillon, 34095 Montpellier Cedex 05, France,Department of Chemistry, Lomonosov Moscow State University Vorob'evy gory, Moscow 119899, Russia;

    Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow ! 79991, Russia;

    Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow ! 79991, Russia;

    Department of Chemistry, Lomonosov Moscow State University Vorob'evy gory, Moscow 119899, Russia;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    poly(ethylene glycol); PEG; catalysis; organometallic chemistry; transition metals; post-transition metals; palladium; copper; lewis acids; nanoparticles; microwaves; cross-coupling; heterocycles; recycling;

    机译:聚乙二醇);PEG;催化;有机金属化学过渡金属;过渡后金属钯;铜;路易斯酸;纳米粒子微波炉;交叉耦合;杂环;回收利用;

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