Silenes: Connectors between classical alkenes and nonclassical heavy alkenes

Henrik Ottosson; Anders M. Ekloef

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Silenes: Connectors between classical alkenes and nonclassical heavy alkenes

机译：硅烷：经典烯烃和非经典重烯烃之间的连接体

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substituents are pivotal in determining which of these structures is adopted. Silene properties, ranging from charge distribution and NMR chemical shifts to reactivities, are strongly connected to the electronic structure of the silene, and thus to its substitution pattern.

机译：取代基对于确定采用这些结构中的哪个至关重要。从电荷分布和NMR化学位移到反应活性的硅烷特性与硅烷的电子结构密切相关，因此与取代图形紧密相关。

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来源
《Coordination chemistry reviews》 |2008年第14期|p.1287-1314|共28页
作者
Henrik Ottosson; Anders M. Ekloef;
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作者单位

Department of Biochemistry and Organic Chemistry, Box 576, Uppsala University, 751 23 Uppsala, Sweden;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
silenes; heavy alkenes; substituent effects; MO theory; silicon; structure and reactivity;

机译：硅烷;重链烯烃;取代基效应;MO理论;硅;结构与反应性;

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1. New systems for classical nitrosohalogenation of alkenes 1.Reactions of alkenes with ethyl nitrite in the presence of phosphorus halides and thionyl chloride [J] . O.B.Bondarenko, A.Yu.Gavrilova, V.N.Tikhanushkina, Russian Chemical Bulletin . 2005,第9期

机译：烯烃经典亚硝基卤化的新体系1.在卤化磷和亚硫酰氯存在下烯烃与亚硝酸乙酯的反应
2. Walking metals: catalytic difunctionalization of alkenes at nonclassical sites [J] . Roshan K. Dhungana, Rishi R. Sapkota, Doleshwar Niroula, Chemical science . 2020,第36期

机译：行走金属：非生物位点烯烃的催化分子化
3. Walking metals: catalytic difunctionalization of alkenes at nonclassical sites [J] . Dhungana Roshan K., Sapkota Rishi R., Niroula Doleshwar, Chemical science . 2020,第36期

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4. Stable Derivatives of New Isomeric Forms of Heavier Group 14 Element Alkene Analogues [C] . Philip P. Powers American Chemical Society . 2006

机译：新异构形式的较重组14元烯类烯类物质的稳定衍生物
5. Guanidinato and amidinato complexes of iridium(I): Synthesis, oxygen and sulfur8 reactivity, and (alkene)peroxo- and (alkene persulfidoiridium(III) intermediates. [D] . Kelley, Matthew Ryan. 2012

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6. Walking metals: catalytic difunctionalization of alkenes at nonclassical sites [O] . Roshan K. Dhungana, Rishi R. Sapkota, Doleshwar Niroula, 2020

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7. Non-classical selectivities in the reduction of alkenes by cobalt-mediated hydrogen atom transfer [O] . Xiaoshen Ma, Seth B. Herzon 2015

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8. Reaction of Chlorosulfonyl Isocyanate (CSI) with Fluorosubstituted Alkenes: Evidence of a Concerted Pathway for Reaction of CSI with Fluorosubstituted Alkenes (Preprint) [R] . Shellhamer, D. F., Davenport, K. J., Hassler, D. M., 2010

机译：氯磺酰异氰酸酯（CsI）与氟取代烯烃的反应：CsI与氟取代烯烃反应的一致路径的证据（预印本）

Silenes: Connectors between classical alkenes and nonclassical heavy alkenes

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