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首页> 外文期刊>Coordination chemistry reviews >Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands
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Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands

机译：具有中性氧和氮供体配体的无水scan，钇，镧系元素和act系元素卤化物络合物

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摘要

Studies on lanthanide and actinide halide complexes with neutral O- and/or N-donor ligands have intensified in recent years due to their implications in homogeneous catalysis, magnetic and optical materials, as synthons for the synthesis of novel coordination and organometallic compounds and, for Ln(II) halide complexes, as reducing agents in organic synthesis. Synthetic strategies, structural diversity as well as some important properties and reactivities of these anhydrous metal (including scandium and yttrium) halide complexes are reviewed here. These complexes also hold potential as starting materials for constructing more sophisticated heterometallic assemblies by crystal engineering; the compounds of this class, either discrete ion-pairs or coordination polymers, being discussed separately under the heading heterometallic lanthanide and actinide halide complexes. The aim of this article is to provide a reference text for the researchers working in the lanthanide and actinide coordination chemistry field and to identify and signify the area of future research.
机译：近年来，由于它们在均相催化，磁性和光学材料中作为合成新型配位化合物和有机金属化合物的合成子，它们对具有中性O和/或N供体配体的镧系元素和act系元素卤化物配合物的研究已得到加强。 Ln（II）卤化物络合物，作为有机合成中的还原剂。综述了这些无水金属（包括scan和钇）卤化物配合物的合成策略，结构多样性以及一些重要的性质和反应活性。这些配合物还具有作为通过晶体工程构建更复杂的异金属组件的起始材料的潜力。这类化合物，离散的离子对或配位聚合物，将分别在杂金属镧系元素和act系元素卤化物配合物下进行讨论。本文旨在为镧系和act系配位化学领域的研究人员提供参考资料，并确定和表明未来的研究领域。

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