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Synthesis and application of chiral monodentate phosphines in asymmetric hydrogenation

机译:手性单齿膦的不对称加氢合成及应用

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摘要

Chiral monodentate phosphines ligands were the first ligands to be investigated in the field of asymmetric hydrogenation. After years of neglect, these ligands have recently experienced a new renaissance. This review discusses the structural design of the most successful monodentate phosphines and, following a historical line, reports on their application in the asymmetric hydrogenation of C=C and C=O bonds.
机译:手性单齿膦配体是不对称氢化领域中第一个被研究的配体。经过多年的忽视,这些配体最近经历了新的复兴。这篇评论讨论了最成功的单齿膦的结构设计,并遵循历史路线,报道了它们在C = C和C = O键不对称氢化中的应用。

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