Lanthanoid(Ⅱ) tetraphenylborate complexes: From discrete ions to pseudo metallocenes

Glen B. Deacon; David J. Evans; Craig M. Forsyth; Peter C. Junk

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Lanthanoid(Ⅱ) tetraphenylborate complexes: From discrete ions to pseudo metallocenes

机译：镧系（Ⅱ）四苯基硼酸盐配合物：从离散离子到假茂金属

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This article describes the synthetic strategies, structural features and reactivity of a unique class of discrete cationic lanthanoid(Ⅱ) complexes with tetraphenylborate counter ions. In addition, variable binding of these 'weakly coordinating anions' (WCA) to the large electropositive f-element metal cations can also occur.

机译：本文描述了一类独特的离散阳离子镧系元素（Ⅱ）与四苯基硼酸根抗衡离子的合成策略，结构特征和反应性。此外，这些“弱配位阴离子”（WCA）与大型电正性f元素金属阳离子的可变结合也可能发生。

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来源
《Coordination chemistry reviews》 |2007年第14期|1699-1706|共8页
作者
Glen B. Deacon; David J. Evans; Craig M. Forsyth; Peter C. Junk;
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作者单位

School of Chemistry, Monash University, Clayton, Victoria 3800, Australia;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
lanthanoids; lanthanoid(Ⅱ); tetraphenylborate; weakly coordinating anions; rare earths;

机译：镧系元素;镧系元素（Ⅱ）;硼酸四苯酯弱配位阴离子;稀土;

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1. Lanthanoid(II) tetraphenylborate complexes: From discrete ions to pseudo metallocenes [J] . Glen B. Deacon, David J. Evans, Craig M. Forsyth, Coordination chemistry reviews . 2007,第13a14期

机译：镧系元素（II）四苯基硼酸盐络合物：从离散离子到假茂金属
2. eta~6:eta~6Coordination of Tetraphenylborate to Ytterbium(n): A New Class of Lanthanoid ansa-Metallocenes [J] . Glen B.Deacon, Craig M.Forsyth, Peter C.Junk European journal of inorganic chemistry . 2005,第5期

机译：eta〜6：eta〜6硼酸四苯酯与Y的配位：新型镧系元素ansa-茂金属
3. Contrasting binding modes in lanthanoid pyrazolate and pseudo-pyrazolates prepared by oxidation of lanthanoid(II) complexes and lanthanoid metals with thallium(I) reagents [J] . Deacon GB., Fallon GD., Jones C., Organometallics . 2000,第9期

机译：用镧（I）试剂氧化镧系元素（II）配合物和镧系元素金属制得的镧系元素吡唑酸盐和拟吡唑酸盐的对比结合模式
4. Luminescent Single-Ion Magnets from Lanthanoid(III) Complexes with Monodentate Ketone Ligands [C] . Takuya Kanetomo, Takayuki Ishida Irago Conference . 2016

机译：来自镧（III）配合物的发光单离子磁铁与单齿酮配体
5. Coordinative unsaturation in chiral organolanthanides: A synthetic and asymmetric catalytic mechanistic study of yttrium and lutetium Ansa-metallocene complexes having pseudo-meso ancillary ligation. [D] . Haar, Christopher Michael. 1995

机译：手性有机镧系元素中的配位不饱和：具有假介观辅助连接的钇和Ansa-茂金属络合物的合成和不对称催化机理研究。
6. K-edge XANES investigation of octakis(DMSO)lanthanoid(III) complexes in DMSO solution and solid iodides [O] . Paola D’Angelo, Valentina Migliorati, Riccardo Spezia, -1

机译：DMSO溶液和固体碘化物中的八（DMSO）镧系元素（III）配合物的K-edge XANES研究
7. Structures of Lanthanoid Complexes of Glyceric Acid, Gluconic Acid, and Lactobionic Acid from the Lanthanoid-Induced1H NMR Shifts: pH Dependence of the Lanthanoid-Substrate Equilibria [O] . Tooru Taga, Yoshihiro Kuroda, Makoto Ohashi 1978

机译：来自镧系元素诱导的1H NMR偏移的甘氨酸，葡萄糖酸，含叶酸的镧系元素的结构：Lanthanoid - 衬底平衡的pH依赖性
8. A Discrete Ordinate Technique for the Non-Linear Boltzmann Equation with Application to Pseudo-Shock Relaxation [R] . Wachman, M., Hamel, B. B. 1966

机译：应用于伪冲击弛豫的非线性Boltzmann方程的离散纵标技术

Lanthanoid(Ⅱ) tetraphenylborate complexes: From discrete ions to pseudo metallocenes

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