Metal ion catalysis in acyl and phosphoryl transfer: Transition states as ligands

Anatoly K. Yatsimirsky

首页> 外文期刊>Coordination chemistry reviews >Metal ion catalysis in acyl and phosphoryl transfer: Transition states as ligands

【24h】

Metal ion catalysis in acyl and phosphoryl transfer: Transition states as ligands

机译：酰基和磷酰基转移中的金属离子催化：过渡态作为配体

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Interpretation of the role of metal ions in catalysis in terms of direct binding of the catalyst to the transition state of the uncatalyzed reaction allows one to view transition states as ligands and to apply the concepts elaborated for analysis of stability of coordination compounds to reactivity. This paper reviews recent results on kinetics of metal ion catalyzed hydrolysis of carboxylic acid and phosphate esters providing pseudo-equilibrium transition state complexation constants (K_T~≠) for approximately 130 reactions. General trends in K_T~≠ values, in particular, interrelations between ground state and transition state complexation for different groups of catalysts and reactions are discussed.

机译：解释金属离子在催化剂中的作用，即催化剂与未催化反应的过渡态的直接结合，使人们可以将过渡态视为配体，并将阐述的概念用于分析配位化合物对反应性的稳定性。本文综述了有关金属离子催化的羧酸和磷酸酯水解动力学的最新研究结果，提供了约130个反应的拟平衡过渡态络合常数（K_T〜≠）。讨论了K_T〜≠值的一般趋势，特别是针对不同组的催化剂和反应的基态与过渡态络合之间的相互关系。

著录项

来源
《Coordination chemistry reviews》 |2005年第18期|p.1997-2011|共15页
作者
Anatoly K. Yatsimirsky;
展开▼
作者单位

Facultad de Quimica, Universidad National Autonoma de Mexico, 04510 Mexico D.F., Mexico;

展开▼
收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
catalysis; transition state; hydrolysis;

机译：催化;过渡态;水解;

相似文献

外文文献
中文文献
专利

1. Two-Metal Ion Catalysis in Enzymatic Acyl- and Phosphoryl-Transfer Reactions [J] . Norbert Strater, William N. Lipscomb, Thomas Klabunde, Angewandte Chemie . 1996,第18期

机译：酶促酰基和磷酰基转移反应中的两金属离子催化
2. Bio-inspired approaches to accelerating metal ion-promoted reactions: enzyme-like rates for metal ion mediated phosphoryl and acyl transfer processes [J] . Brown Robert Stan Pure and Applied Chemistry . 2015,第6期

机译：生物启发的方法来加速金属离子促进的反应：金属离子介导的磷酰基和酰基转移过程的酶样速率
3. Integrating Catalyst and Co-Catalyst Design in Olefin Polymerization Catalysis:Transferable Dianionic Ligands for the Activation of Late Transition Metal Polymerization Catalysts [J] . Mikael Brasse, Juan Campora, Maxwell Davies Advanced synthesis & catalysis . 2007,第13期

机译：烯烃聚合催化中催化剂和助催化剂的集成设计：可转移的阳离子型配体，用于活化后期过渡金属聚合催化剂
4. Chiral Control of Transition Metal Complexes Bearing Atropos but Achiral Ligands:Their Application to Asymmetric Catalysis [C] . Kohsuke Aikawa, Koichi Mikami Symposium on Organometallic Chemistry . 2003

机译：过渡金属复合物的手性控制轴承ATROPOS，但甲状腺配体：它们在不对称催化作用的应用
5. Model compounds for the investigation of phosphoryl transfer to metal-hydroxide and acyl transfer to metal-peroxide species. [D] . Pfleider, Aileen Monica. 1993

机译：用于研究磷酰基转移至金属氢氧化物和酰基转移至金属过氧化物物质的模型化合物。
6. Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis [O] . Jingran Tao, Li-Mei Jin, X Peter Zhang 2014

机译：Co（II）基金属铁催化通过烯烃与磷叠氮化物的对映选择性叠氮化将手性N-磷酰基氮丙啶合成
7. Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis [O] . Jingran Tao, Li-Mei Jin, X. Peter Zhang 2014

机译：通过基于Co（II）的金属自由基催化剂，通过对苯二甲酰基与磷酰基叠氮化物的对映选择性氮丙啶化合成手性N，N-磷酰基氮丙啶
8. Ligand Transformations and Catalysis by Transition Metal Cluster Compounds Containing Sulfur: Progress Report, 1986-1988. [R] . Adams, R. D. 1988

机译：含硫过渡金属簇化合物的配体转化和催化：进展报告，1986-1988。

Metal ion catalysis in acyl and phosphoryl transfer: Transition states as ligands

摘要

著录项

相似文献

相关主题

期刊订阅