Unusual metal centres/coordination spheres in spin crossover compounds

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Unusual metal centres/coordination spheres in spin crossover compounds

机译：自旋交联化合物中异常的金属中心/配位球

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The most widely studied spin crossover (SCO) systems are those involving hexacoordinate iron(II) complexes immerse in the "magic" N-6 coordination sphere. In this review the properties of SCO-active metal complexes containing unusual metal centres and/or coordination spheres are analysed, except for Fe3+ complexes that have been recently reviewed. The SCO-properties of the less studied SCO metal centres Cr2+, Mn2+, Mn3+ and Co2+ are presented, showing great advances in the development of bistable materials containing first row transition metals other than Fe. Finally, an analysis of the changes in the structural parameters, bond lengths and angles, during the spin conversion is presented for those complexes structurally characterised by X-ray crystallography in both high- and low-spin states. (C) 2019 Elsevier B.V. All rights reserved.

机译：研究最广泛的自旋交叉（SCO）系统是涉及浸入“魔术” N-6配位球中的六配位铁（II）配合物的系统。在这篇综述中，分析了含有异常金属中心和/或配位球的SCO活性金属配合物的性能，但最近已综述的Fe3 +配合物除外。提出了较少研究的SCO金属中心Cr2 +，Mn2 +，Mn3 +和Co2 +的SCO性质，显示了在开发除Fe以外的第一行过渡金属的双稳态材料方面的重大进展。最后，对自旋转换过程中在高旋态和低旋态下通过X射线晶体学表征的那些配合物的结构参数，键长和角度的变化进行了分析。（C）2019 Elsevier B.V.保留所有权利。

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《Coordination chemistry reviews》 |2020年第3期|213148.1-213148.30|共30页
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IPN Ctr Invest & Estudios Avanzados Dept Quim Ave 1PN 2508 Mexico City 07360 DF Mexico;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Spin crossover; Manganese; Cobalt; Chromium; Bistable complexes; HS and LS complexes;

机译：旋转交叉;锰;钴;铬;双稳态复合体;HS和LS复合物;

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1. One-Dimensional Thiocyanato-Bridged Fe(II) Spin Crossover Cooperative Polymer With Unusual FeN5S Coordination Sphere [J] . Nebbali Kahina, Mekuimemba Cle Donacier, Charles Catherine, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第19期

机译：一维硫代氰酸盐桥接Fe（II）旋转交叉协作聚合物，具有异常的FEN5S协调领域
2. Quantum chemical modeling of magnetically bistable metal coordination compounds. Synchronization of spin crossover, valence tautomerism and charge transfer induced spin transition mechanisms [J] . Minkin V. I., Starikova A. A., Starikov A. G. Dalton transactions: An international journal of inorganic chemistry . 2016,第30期

机译：磁性双稳态金属配位化合物的量子化学建模。自旋交叉，价互变异构和电荷转移引起的自旋跃迁机制的同步
3. Thermodynamic properties of spin crossover 3d-metal coordination compounds [J] . G. A. Berezovskii, L. G. Lavrenova Journal of Thermal Analysis and Calorimetry . 2011,第3期

机译：自旋交联3d-金属配位化合物的热力学性质
4. Spin-crossover and Unusual Magnetization Behavior in Novel Cobalt and Iron Coordination Polymers of Pyridazine [C] . Tao Yi, Susumu Kitagawa, Katsunori Mochizuki, China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena . 2000

机译：吡啶啶新钴和铁配位聚合物中的旋转交叉和异常磁化行为
5. Spin -crossover compounds and linear metal -radical chains: Magnetism and structure [D] . Hibbs, Wendy Lorraine Hoffman 2002

机译：自旋交联化合物和线性金属自由基链：磁性和结构
6. Coordination sphere of the third metal site is essential to the activity and metal selectivity of alkaline phosphatases [O] . Dimitris Koutsioulis, Andrzej Lyskowski, Seija Mäki, 2010

机译：第三金属位点的配位球对于碱性磷酸酶的活性和金属选择性至关重要
7. Cooperative Iron(II) Spin Crossover Complexes with N4O2 Coordination Sphere [O] . -1

机译：合作铁（II）与N4O2配位球的旋转交叉复合物
8. Investigation of the Second Coordination Sphere in Inorganic Complexes by Dynamic Nuclear Polarization (Dnp). Complexes with Electron Spin Residing on the Metal Atom. [R] . Wagner, B. E., Bates, R. D., Poindexter, E. H. 1974

机译：用动态核极化（Dnp）研究无机配合物中的第二配位球。金属原子上的电子自旋复合物。

Unusual metal centres/coordination spheres in spin crossover compounds

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