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Emergence of anion-π interactions: The land of opportunity in supramolecular chemistry and beyond

机译：Anion-π相互作用的出现：超分子化学和超越的机会之地

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摘要

The anion-pi interaction, a non-covalent attractive force between hosts (electron-deficient arenes) and guests (anions) besides having many turns and surprises has recently turned into a vital supramolecular interaction. Over the past few years, it has become more and more attractive due to its applicability in diverse areas of research such as molecular recognition, sensing, biomembrane transport, catalysis and also in designing of novel selective anion-receptors. Therefore, the collection of the progress related to this non-covalent interaction is well overdue and extremely desirable to the research community. To this context, we planned to report the detailed developments of this wonderful interaction since its involvement into the supramolecular family. This particular review article in beginning provide the basic fundamentals of these interactions by means of theoretical, computational, and experimental investigations followed by the concept of additivity, directionality, and heptacity. Lastly, we have focused to cover its impact in different fields ranging from metal-organic frameworks, organic electronics, and molecular self-assemblies to the biological sciences. We believe that the present account will surely offer a new dimension to anion-pi interaction and we are pretty sure that the readers will be benefitted from this review article. (C) 2020 Elsevier B.V. All rights reserved.
机译：除了具有许多转弯和惊喜之外的主体（电子缺陷阶段）和客人（阴离子）之间的非共价吸引力，最近变成了重要的超分子相互作用。在过去几年中，由于其在不同研究领域的适用性，例如分子识别，传感，生物膜运输，催化和设计的新选择性阴离子受体等各种研究领域，它已经变得越来越有吸引力。因此，与这种非共价相互作用有关的进步的收集是逾期的，对研究界非常理想。为此背景下，我们计划报告这种美妙互动的详细发展，因为它的参与进入超分子家庭。这篇特殊的审查文章在开始提供了这些相互作用的基本基础，通过理论，计算和实验研究，其次是添加性，方向性和术的概念。最后，我们专注于覆盖其在不同领域的影响，从金属有机框架，有机电子和分子自我组件到生物科学。我们认为，本账户肯定会为Anion-PI互动提供新的维度，我们非常肯定读者将受益于此审查文章。 （c）2020 Elsevier B.v.保留所有权利。

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