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myo-inositol hexakisphosphate: Coordinative versatility of a natural product

机译:肌醇硫代磷酸:天然产品的协调多功能性

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摘要

myo-inositol phosphates are an important group of biomolecules that are present in the eukaryotic cells. The most abundant member of this family in nature is InsP(6), usually called phytate. The importance of the interaction of InsP(6) with cations has been recognized during the last years, and any attempt to know the function of this molecule in eukaryotic cells must include the fact that phytate will be strongly associated with simple inorganic and organic ammonium cations in solution. On the other hand, slightly soluble salts play an important role in phosphorous storage in plant kingdom and organophosphates found in soils. This review compiles the efforts during the last ten years to quantify and understand the interaction of InsP(6) with different cations, either in solution or in the formation of solid phases. A coordination chemistry's view is used to describe the interaction of this versatile ligand with cations and organic amines, and how they can determine the self-assembly process in the formation of polynuclear complexes and solid phases. (C) 2020 Elsevier B.V. All rights reserved.
机译:肌醇肌醇磷酸盐是真核细胞中存在的重要生物分子组。本家庭中最丰富的成员是Insp(6),通常被称为植物。在过去几年中,isp(6)与阳离子相互作用的重要性,并且任何发现在真核细胞中的该分子功能的尝试必须包括植物植物将与简单的无机和有机铵阳离子密切相关的事实在解决方案中。另一方面,微溶于盐在植物王国和土壤中发现的有机磷中发挥着重要作用。本次审查汇总了在过去十年中的努力,以量化和了解isp(6)与不同阳离子的互动,无论是在溶液中还是在形成固相。协调化学的视图用于描述这种通用配体与阳离子和有机胺的相互作用,以及它们如何确定多核配合物和固相的形成自组装过程。 (c)2020 Elsevier B.v.保留所有权利。

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