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Redox-active ligands: Recent advances towards their incorporation into coordination polymers and metal-organic frameworks

机译：氧化还原活性配体：最近进入其融入协调聚合物和金属有机框架的进步

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摘要

Over the past three decades, the field of coordination polymers (CPs) and metal-organic frameworks (MOFs) has developed rapidly due to the potential applications of these materials in gas storage, separations, catalysis and switching. Introducing redox properties into CPs and MOFs to electrochemically modulate their properties for the development of solid state electronic devices has been an interesting strategy applied in recent years. Notably, a challenge within this area is the engineering of framework materials with desired redox properties targeted at a specific function. This review explores some of the key redox-active ligands that have been investigated within the previous eight years as redoxactive components of solid state materials and examines a number of key strategies for their integration into CPs and MOFs. This review further highlights emergent redox-active ligands in the literature, which take inspiration from the rich field of organic electronics. While these ligands remain largely unexplored in the field of MOFs and CPs, they offer new opportunities for the improvement of solar cells, light induced photo switches, efficient photoelectrocatalysts and long range, rapid charge transfer in MOF materials. (C) 2021 Elsevier B.V. All rights reserved.
机译：在过去的三十年中，由于这些材料在气体储存，分离，催化和切换中的潜在应用，协调聚合物（CPS）和金属 - 有机框架（MOF）的开发迅速发展。将氧化还原性能引入CPS和MOFS以电化学调节其用于开发固态电子设备的性能，这是近年来应用的有趣策略。值得注意的是，该领域内的挑战是骨架材料的工程，具有所需的氧化还原性能，靶向特定功能。该审查探讨了在前八年内被调查的一些关键的氧化还原活性配体，作为固态材料的氧化烃组件，并检查他们融入CPS和MOF的许多关键策略。本综述进一步突出了文献中的新兴氧化还原活性配体，这取得了丰富的有机电子领域的灵感。虽然这些配体在MOF和CPS领域仍然是未开发的，但它们为改善太阳能电池，光诱导的光电开关，高效光电催化剂和长距离，虽然为MOF材料提供了新的机会。 （c）2021 Elsevier B.v.保留所有权利。

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