Electrochemical and optical properties of a redox-active Cu(ii) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand

Hua C.; Turner P.; DAlessandro D.M.

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Electrochemical and optical properties of a redox-active Cu(ii) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand

机译：带有三（4-（吡啶-4-基）苯基）胺配体的氧化还原活性Cu（ii）配位骨架的电化学和光学性质

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A new redox-active ligand, tris(4-(pyridin-4-yl)phenyl)amine (Npy _3), has been synthesised, and incorporated into the coordination framework [Cu(Npy_3)Cl_2]·DMF. The monoradical cation of the ligand is readily accessible, thus enabling chemical oxidation of the framework. The novel Npy_3 ligand has significant potential as a structural motif for the development of multifunctional frameworks.

机译：合成了一种新的氧化还原活性配体三（4-（吡啶-4-基）苯基）胺（Npy _3），并将其引入配位构架[Cu（Npy_3）Cl_2]·DMF。配体的单自由基阳离子是易于接近的，因此使得骨架的化学氧化成为可能。新型Npy_3配体具有巨大的潜力，可作为开发多功能框架的结构基序。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第18期|共4页
作者
Hua C.; Turner P.; DAlessandro D.M.;
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tris(4-(pyridin-4-yl)phenyl); Electrochemical; Cu(Npy_3)Cl_2·DMF;

机译：三（4-（吡啶-4-基）苯基）;电化学;[Cu（Npy_3）Cl_2]·DMF;

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1. Electrochemical and optical properties of a redox-active Cu(ii) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand [J] . Hua C., Turner P., DAlessandro D.M. Dalton transactions: An international journal of inorganic chemistry . 2013,第18期

机译：带有三（4-（吡啶-4-基）苯基）胺配体的氧化还原活性Cu（ii）配位骨架的电化学和光学性质
2. Facile redox state manipulation in Cu(I) frameworks by utilisation of the redox-active tris(4-(pyridin-4-yl)phenyl)amine ligand [J] . Hua Carol, Turner Peter, DAlessandro Deanna M. Dalton transactions: An international journal of inorganic chemistry . 2015,第34期

机译：通过利用氧化还原活性的三（4-（吡啶-4-基）苯基）胺配体在Cu（I）框架中轻松进行氧化还原状态操纵
3. Redox-state investigation in a Co(II) framework with the redox-active tris(4-(pyridin-4-yl) phenyl) amine ligand [J] . Hua Carol, DAlessandro Deanna M. Supramolecular chemistry . 2015,第11a12期

机译：具有氧化还原活性的三（4-（吡啶-4-基）苯基）胺配体的Co（II）框架中的氧化还原状态研究
4. Synthesis, characterization and emission properties of yttrium(III), europium(III), and terbium(III) complexes of tris(2-(2-hydroxy-3- trifluoromethoxylbenzylideneamino)ethyl)amine [C] . Masatoshi Kanesato, Yoshihiro Kikkawa, Midori Goto Rare Earth Research Conference . 2011

机译：钇（III），铕（III）和三（2-（2-（2-（2-羟基-3-三氟甲氧基苄基苄基）乙基）胺的合成，铕（III）和铽（III）复合物的合成，表征和排放性能
5. I. The synthesis and coordination chemistry of novel 1,1,1-tris(aminomethyl)ethane (TAME) derived ligands and their use as size selective fluorescent zinc(II) sensors. II. The synthesis of strongly and weakly binding ligands with nitrogen, oxygen, and sulfur-donor groups to be used as receptors in fluorescent ratiometric indicators for transition metal ions. [D] . Kennedy, Daniel Patrick. 2007

机译：I.新型1,1,1-三（氨基甲基）乙烷（TAME）衍生的配体的合成和配位化学及其作为尺寸选择荧光锌（II）传感器的用途。二。具有氮，氧和硫供体基团的强结合和弱结合配体的合成，将用作过渡金属离子的荧光比率指示剂中的受体。
6. 4-(4-Fluorophenyl)-1-phenyl-3-(pyridin-4-yl)-1H-pyrazol-5-amine [O] . Bassam Abu Thaher, Pierre Koch, Dieter Schollmeyer, 2012

机译：4-（4-氟苯甲酰基）-1-苯基-3-（吡啶-4-基）-1H-吡唑-5-胺
7. In Situ Spectroelectrochemical Investigations of the Redox-Active Tris[4-(pyridin-4-yl)phenyl]amine Ligand and a Zn(2+) Coordination Framework [O] . Hua, Carol, Baldansuren, Amgalanbaatar, Tuna, Floriana, 2016

机译：氧化还原活性三[4-（吡啶-4-基）苯基]胺配体和Zn（2+）配位框架的原位光谱电化学研究

Electrochemical and optical properties of a redox-active Cu(ii) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand

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