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Characterisation of rust on microalloyed rail steel exposed to coastal location in India

机译:印度沿海地区暴露的微合金钢的锈蚀特征

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摘要

The rusts on the gauge face and non-gauge face of two rail steels (traditional C-Mn and novel Cu-Mo rail steel) were characterised after two years of service to corelate with an apparent visual observation of a lower corrosion rate in the case of the Cu-Mo rails. Rust samples were characterised by X-ray diffraction, Fourier transform infrared spectroscopy and Mössbauer spectroscopy. X-ray diffraction patterns showed diffuse peaks indicating poorly crystallised rust phases, while the phases identified by the other techniques were γ-FeOOH (lepidocrocite), α-FeOOH (goethite), Fe3-xO4 (magnetite), δ-FeOOH and α-Fe2O3 (haematite). The enhanced corrosion of the gauge face compared to non-gauge face for both rails and that of C-Mn rails compared to Cu-Mo rails was related to the higher amount of γ-FeOOH and lower amount of Fe3-xO4.
机译:两种钢轨(常规C-Mn和新型Cu-Mo钢轨)的轨距表面和非规距表面上的锈蚀的特征是经过两年的服务以进行核化,并通过肉眼观察到了较低的腐蚀速率。的铜钼导轨。通过X射线衍射,傅立叶变换红外光谱和Mössbauer光谱对锈样品进行表征。 X射线衍射图显示出扩散峰,表明结晶相较差,而其他技术鉴定出的相为γ-FeOOH(锂铁云母),α-FeO​​OH(针铁矿),Fe 3-x O < sub> 4 (磁铁矿),δ-FeOOH和α-Fe 2 O 3 (赤铁矿)。两种钢轨的轨距面相比于非规距面的腐蚀增强,C-Mn钢轨与Cu-Mo钢轨相比腐蚀的增强与较高的γ-FeOOH含量和较低的Fe <3-x O 4

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  • 来源
    《Corrosion Engineering, Science and Technology》 |2009年第4期|275-279|共5页
  • 作者单位

    Department of Materials and Metallurgical Engineering, Indian Institute of Technology, Kanpur 208016, India;

    Department of Materials and Metallurgical Engineering, Indian Institute of Technology, Kanpur 208016, India, Email: bala@iitk.ac.in;

    Department of Materials and Metallurgical Engineering, Indian Institute of Technology, Kanpur 208016, India;

    R & D Centre for Iron and Steel, Steel Authority of India Limited, Ranchi 834002, India;

    R & D Centre for Iron and Steel, Steel Authority of India Limited, Ranchi 834002, India;

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