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首页> 外文期刊>Corrosion science >Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS
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Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS

机译:XPS和TOF-SIMS的赤脂蛋白高熵合金表面氧化物及腐蚀行为研究

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摘要

XPS and ToF-SIMS analysis have been combined with electrochemical measurements to determine the corrosion behavior of the equiatomic CoCrFeMnNi high entropy alloy. An XPS methodology based on analysis of the 3p core level spectra was developed to determine the composition and thickness of oxide films. Both native oxide ( similar to 1.4 nm) and passive films (similar to 1.6 nm) formed in acidic medium are duplex, comprising Cr and Mn inner layer and Cr/Fe/Co mixture outer layer. No nickel is observed in the oxide layer. The effects of exposure of the native film to sulfuric acid and passivation under anodic polarization have been investigated.
机译:XPS和TOF-SIMS分析已与电化学测量结合,以确定赤型COCRFEMNNI高熵合金的腐蚀行为。开发了一种基于3P核心水平光谱分析的XPS方法,以确定氧化膜的组成和厚度。在酸性介质中形成的天然氧化物(类似于1.4nm)和无源膜(类似于1.6nm)是双链体,包含Cr和Mn内层和Cr / Fe / Co混合物外层。在氧化物层中没有观察到镍。研究了海底膜暴露于硫酸和钝化偏振下的钝化的影响。

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  • 来源
    《Corrosion science》 |2020年第5期|108507.1-108507.10|共10页
  • 作者单位

    PSL Univ Chim ParisTech CNRS Inst Rech Chim Paris Phys Chem Surfaces Grp F-75005 Paris France;

    PSL Univ Chim ParisTech CNRS Inst Rech Chim Paris Phys Chem Surfaces Grp F-75005 Paris France;

    PSL Univ Chim ParisTech CNRS Inst Rech Chim Paris Phys Chem Surfaces Grp F-75005 Paris France;

    PSL Univ Chim ParisTech CNRS Inst Rech Chim Paris Phys Chem Surfaces Grp F-75005 Paris France;

    Univ Paris Est Creteil CNRS ICMPE UMR7182 F-94320 Thiais France;

    Univ Paris Est Creteil CNRS ICMPE UMR7182 F-94320 Thiais France;

    Univ Paris Est Creteil CNRS ICMPE UMR7182 F-94320 Thiais France;

    PSL Univ Chim ParisTech CNRS Inst Rech Chim Paris Phys Chem Surfaces Grp F-75005 Paris France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    High entropy alloy; Oxide film; Passivation; XPS; ToF-SIMS;

    机译:高熵合金;氧化物膜;钝化;XPS;TOF-SIMS;

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