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TOXINS IN HONEY - A STUDY BY ICP-MS

机译:蜂蜜中的毒素-ICP-MS研究

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This paper represents a benchmark study that compares trace toxic elemental concentrations in honey products fromvarious countries to establish a set of guidelines against which subsequent honey analyses could be referenced. Honey isa popular food item, widely consumed as part of a dietary regimen. Honey products originating from nine differentcountries were analyzed for toxic trace elements following microwave digestion in mild acid media (3% HNO3). Acomparative study of this nature has not been previously reported and could provide useful data particularly from anenvironmental and nutritional perspective. High-performance ICP-MS was employed to examine the levels of a range ofnoxious elements in aqueous samples. The performance of the instrument was validated using certified referencestandards. Minor fluctuations in performance were adjusted by use of an internal standard. Sixteen elements wereselected for investigation and the mean concentration ranges are summarized as follows: Li, Be, Ag, Cd, Sb, Hg, Tl, Bi,Th, U occurred in the range 1-25 ?g/L; Pb, Se V, Ni, Cr, Al were observed in the interval 0.1- 4 mg/L. These toxins tendto originate from natural flora associated with the honey or from the chemical processes linked to the production ofhoney. In some samples a€?spikesa€? or elevated elemental levels were observed, which could be used to identify ora€?fingerprinta€? the country of origin of the corresponding honey sample. Our work could be considered a valuable sourceof reference data, and could contribute to environmental, food and forensic science.
机译:本文代表了一项基准研究,该研究比较了来自不同国家的蜂蜜产品中痕量有毒元素的浓度,从而建立了一套可以参考后续蜂蜜分析的准则。蜂蜜是一种流行的食品,是饮食中广泛食用的一种食品。在温和的酸性介质(3%HNO3)中微波消化后,分析了来自九个不同国家的蜂蜜产品中的痕量微量元素。此前尚未报道过这种性质的比较研究,它可以提供有用的数据,尤其是从环境和营养的角度来看。高性能ICP-MS用于检测水性样品中一系列有害元素的水平。仪器的性能已通过认证的参考标准进行了验证。通过使用内部标准来调整性能的细微波动。选择了16种元素进行研究,其平均浓度范围总结如下:Li,Be,Ag,Cd,Sb,Hg,Tl,Bi,Th,U的浓度范围为1-25 µg / L。在0.1-4 mg / L的间隔内观察到Pb,Se V,Ni,Cr,Al。这些毒素往往来自与蜂蜜有关的天然菌群或与蜂蜜生产有关的化学过程。在某些样本中,或观察到元素水平升高,可用于识别口印或指纹。相应蜂蜜样品的原产国。我们的工作可以被认为是参考数据的宝贵来源,并且可以为环境,食品和法医科学做出贡献。

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