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Advanced Energy Storage Devices: Basic Principles, Analytical Methods, and Rational Materials Design

机译:先进的储能设备:基本原理,分析方法和合理的材料设计

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Tremendous efforts have been dedicated into the development of high‐performance energy storage devices with nanoscale design and hybrid approaches. The boundary between the electrochemical capacitors and batteries becomes less distinctive. The same material may display capacitive or battery‐like behavior depending on the electrode design and the charge storage guest ions. Therefore, the underlying mechanisms and the electrochemical processes occurring upon charge storage may be confusing for researchers who are new to the field as well as some of the chemists and material scientists already in the field. This review provides fundamentals of the similarities and differences between electrochemical capacitors and batteries from kinetic and material point of view. Basic techniques and analysis methods to distinguish the capacitive and battery‐like behavior are discussed. Furthermore, guidelines for material selection, the state‐of‐the‐art materials, and the electrode design rules to advanced electrode are proposed.
机译:致力于纳米级设计和混合方法的高性能能量存储设备的开发已经付出了巨大的努力。电化学电容器和电池之间的边界变得不太明显。相同的材料可能会表现出电容性或类电池行为,具体取决于电极设计和电荷存储客体离子。因此,电荷存储时发生的潜在机理和电化学过程可能使该领域的新手以及该领域中的一些化学家和材料科学家感到困惑。这篇综述从动力学和材料的角度提供了电化学电容器和电池之间相似性和差异性的基础。讨论了区分电容和类电池行为的基本技术和分析方法。此外,还提出了材料选择指南,最新材料以及针对高级电极的电极设计规则。

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