Metal–Organic Framework MIL-101(Cr) as an Efficient Heterogeneous Catalyst for Clean Synthesis of Benzoazoles

Esmaeil Niknam; Farhad Panahi; Fatemeh Daneshgar; Foroogh Bahrami; Ali Khalafi-Nezhad

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Metal–Organic Framework MIL-101(Cr) as an Efficient Heterogeneous Catalyst for Clean Synthesis of Benzoazoles

机译：金属有机骨架MIL-101（Cr），是清洁合成苯并恶唑的高效多相催化剂

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A metal–organic framework [MIL-101(Cr)] was used as an efficient heterogeneous catalyst in the synthesis of benzoazoles (benzimidazole, benzothiazole, and benzoxazole), and quantitative conversion of products were obtained under optimized reaction conditions. The catalyst could be simply extracted from the reaction mixture, providing an efficient and clean synthetic methodology for the synthesis of benzoazoles. The MIL-101(Cr) catalyst could be reused without a remarkable decrease in its catalytic efficiency.

机译：金属有机骨架[MIL-101（Cr）]被用作苯并唑（苯并咪唑，苯并噻唑和苯并恶唑）合成中的高效多相催化剂，并在优化的反应条件下获得了产物的定量转化率。可以简单地从反应混合物中提取催化剂，从而为合成苯并唑提供了一种高效，清洁的合成方法。 MIL-101（Cr）催化剂可以重复使用而不会明显降低其催化效率。

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《ACS Omega》 |2018年第12期|共10页
作者
Esmaeil Niknam; Farhad Panahi; Fatemeh Daneshgar; Foroogh Bahrami; Ali Khalafi-Nezhad;
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中图分类化学;
关键词
Carbonyl compounds (organic)CatalystsHeterocyclic compoundsMetal-organic frameworksSolvation;

机译：羰基化合物（有机）催化剂杂环化合物金属有机骨架溶剂化;

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1. Au 3+ /Au 0 Supported on Chromium(III) Terephthalate Metal Organic Framework (MIL-101) as an Efficient Heterogeneous Catalystfor Three-Component Coupling Synthesis of Propargylamines [J] . Lili Liu, Xishi Tai, Xiaojing Zhou Materials . 2017,第2期

机译：对苯二甲酸铬（III）金属有机骨架（MIL-101）负载的Au 3+ / Au 0作为高效多相催化剂，用于炔丙胺的三组分偶联合成
2. Bimetallic Au-Ni alloy nanoparticles in a metal-organic framework (MIL-101) as efficient heterogeneous catalysts for selective oxidation of benzyl alcohol into benzaldehyde [J] . Liu Lili, Tai Xishi, Zhou Xiaojing, Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2019,第期

机译：金属有机骨架（MIL-101）中的双金属Au-Ni合金纳米粒子作为有效的非均相催化剂，用于选择性氧化苄醇纳苯甲醛
3. yy Dodecatungstocobaltate heteropolyanion encapsulation into MIL-101(Cr) metal-organic framework scaffold provides a highly efficient heterogeneous catalyst for methanolysis of epoxides [J] . Marandi Afsaneh, Tangestaninejad Shahram, Moghadam Majid, Applied Organometallic Chemistry . 2018,第2期

机译：YY十二宫霍博酸盐杂化型封装成MIL-101（CR）金属 - 有机框架支架，提供了一种高效的环氧化甲烷解的非均相催化剂
4. BIMETAL-ORGANIC FRAMEWORK SELF-ADJUSTED SYNTHESIS OF SUPPORT-FREE NONPRECIOUS ELECTROCATALYSTS FOR EFFICIENT OXYGEN REDUCTION [C] . Bo You, Yujie Sun ACS National Meeting Exhibition . 2016

机译：双金属 - 有机框架自调节合成无尊重的非佛力电催化剂，用于有效氧还原
5. Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation [D] . Phan, Anh Thi Phuong 2011

机译：金属有机骨架，包括高通量合成沸石咪唑酸酯骨架，及其在二氧化碳捕获，储存和甲烷活化催化剂中的应用
6. Metal–Organic Framework MIL-101(Cr) as an EfficientHeterogeneous Catalyst for Clean Synthesis of Benzoazoles [O] . Esmaeil Niknam, Farhad Panahi, *, 2018

机译：高效的金属有机框架MIL-101（Cr）清洁合成苯并唑的多相催化剂
7. Metal–Organic Framework MIL-101(Cr) as an Efficient Heterogeneous Catalyst for Clean Synthesis of Benzoazoles [O] . Esmaeil Niknam, Farhad Panahi, Fatemeh Daneshgar, 2018

机译：金属有机框架MIL-101（CR）作为清洁合成苯并唑的有效异质催化剂

Metal–Organic Framework MIL-101(Cr) as an Efficient Heterogeneous Catalyst for Clean Synthesis of Benzoazoles

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