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首页> 外文期刊>American journal of applied sciences >Research of the Interacting Process of Copper-Base Alloys with Leaching Solutions under the Action of Different Physicochemical Factors | Science Publications
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Research of the Interacting Process of Copper-Base Alloys with Leaching Solutions under the Action of Different Physicochemical Factors | Science Publications

机译：不同理化因素作用下铜基合金与浸出液的相互作用过程研究科学出版物

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> >Analysis of the current scientificand technical data shows the increased difficulty in innovative solutionsdevelopment for metal extraction from different kinds of mineral raw materials,due to fundamental change in mineral resources base of metallurgy. Apart frompolymetallic ores, complex in chemistry and intractable, the basis for thecurrent mineral resources base is formed by technogenic production waste,so-called recovered materials. The source for nonferrous metals is not onlymineral but also recovered materials. The possibility of copper and zinc extractionfrom recovered materials, particularly from latten, widely-used in technology,has been examined. The article studies influence of different physicochemicalfactors on the process of dissolution of copper-base alloys by cathode andanode polarization of a sulfur-graphite electrode. It is specified that copperand zinc extraction by cathode polarization is 25 and 30% respectively. Duringthe solution process, copper is oxidized and sulfurized and complex zincsulfates are formed, which prevent metals from further dissolution. Electrolyteconcentration, current density and temperature contribute to metal solubilityincrease. It is shown that the difference in leach process of metal alloys andpolymetallic minerals is connected both with metal alloys’ structure andmechanism of metals’ solution in nonorganic aqua solution. The results of thephase analysis prove that sulfide and copper oxides and hydrated zinc sulfate,i.?., zinc dissolution is made via formation of sulfates.
机译： > >对当前科学技术数据的分析表明，由于冶金矿产资源基础的根本变化，从各种矿物原料中提取金属的创新解决方案开发难度越来越大。除了化学性质复杂且难处理的多金属矿石外，当前矿产资源基础还由技术生产废料（所谓的回收材料）构成。有色金属的来源不仅是矿物，而且还包括回收材料。已经研究了从回收材料中提取铜和锌的可能性，特别是从技术广泛使用的羊肚中提取铜和锌的可能性。本文研究了不同理化因素对硫-石墨电极阴极和阳极极化溶解铜基合金过程的影响。规定通过阴极极化提取铜和锌分别为25％和30％。在固溶过程中，铜被氧化和硫化，形成复杂的硫酸锌，从而阻止金属进一步溶解。电解质浓度，电流密度和温度有助于金属溶解度的增加。结果表明，金属合金和多金属矿物在浸出过程中的差异与金属合金的结构以及金属在非有机水溶液中的溶解机理有关。相分析的结果证明，硫化物和氧化铜以及水合的硫酸锌，即锌的溶解是通过形成硫酸盐来实现的。

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