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首页> 外文期刊>International Journal of Electrochemical Science >Effects of y-Ray Irradiation on Electrical and Physico-Chemical Properties of Sulfonated PVDF-HFP/1H-1,2,4-Triazole Proton Conducting Membranes
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Effects of y-Ray Irradiation on Electrical and Physico-Chemical Properties of Sulfonated PVDF-HFP/1H-1,2,4-Triazole Proton Conducting Membranes

机译：y射线辐照对磺化PVDF-HFP / 1H-1,2,4-三唑质子传导膜的电和理化性质的影响

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摘要

A new material for proton conducting electrolyte base on sulfonated poly(vinylidene flouride- hexafluoropropylene) (PVDF-HFP)/1H-1,2,4-Triazole (TriA) membrane operating at low relativehumidity and has capability to self-humidify were investigated. Different concentrations of TriA andsulfamic or amidosulfonic acid (H3NSO3) in PVDF-HFP were prepared. The pores of a porous PVDF- HFP were packed with proton carrier, TriA and sulfamic acid (SFA). The samples were then exposedto -rays of up to 50 kGy. The effects of high energy -rays irradiation onto these proton conductingmembranes have been observed. The surface morphology was analysed by scanning electronmicroscopy (SEM). The ionic conductivity of the irradiated membrane was determined using o o impedance spectroscopy (IS) at different temperatures between 30 C and 100 C. The results showedthat the pores membranes shrinkage after irradiation and proton conductivity of the membraneincreased when the absorbed dose up to 30 kGy and after which the proton conductivity decreasedwith increasing of absorbed dose.
机译：研究了一种基于磺化聚偏二氟乙烯-六氟丙烯（PVDF-HFP）/ 1H-1,2,4-三唑（TriA）膜的质子传导电解质新材料，该材料可在较低的相对湿度下工作并具有自增湿能力。制备了PVDF-HFP中不同浓度的TriA和氨基磺酸或氨基磺酸（H3NSO3）。质子载体，TriA和氨基磺酸（SFA）填充了多孔PVDF-HFP的孔。然后将样品暴露于最高达50 kGy的射线下。已经观察到高能射线辐照在这些质子传导膜上的效果。通过扫描电镜（SEM）分析表面形态。使用oo阻抗谱（IS）在30°C和100°C之间的不同温度下测定辐照膜的离子电导率。结果表明，当吸收剂量达到30 kGy时，辐照后的气孔膜收缩，质子电导率增加。质子传导率随吸收剂量的增加而降低。

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