首页> 外文期刊>International Journal of Electrochemical Science >Synergistic Effect of 2-Amino-5-(Ethylthio)-1,3,4-Thiadiazole and Chloride Ion on Cu Anodic Dissolution in a Phosphate-Based Electrolyte
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Synergistic Effect of 2-Amino-5-(Ethylthio)-1,3,4-Thiadiazole and Chloride Ion on Cu Anodic Dissolution in a Phosphate-Based Electrolyte

机译:2-氨基-5-(乙硫基)-1,3,4-噻二唑与氯离子对铜基磷酸盐在电解液中阳极溶解的协同作用

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In this work, the synergistic effect of 2-amino-5-(ethylthio)-1,3,4-thiadiazole (AETD) and chloride ion- (Cl ) in a phosphate-based electrolyte was systemically studied. The results from X-ray photoelectron- spectrometer indicate that Cl was indeed incorporated into the AETD-containing passive film.- According to extensive electrochemical and material analyses, the inhibition capability of the Cl - incorporated AETD passive film demonstrated superior corrosion resistance for Cu anodic dissolutioncompared the AETD passive film alone due to the formation of dense passive film. Additionally, the- combined of AETD and Cl in the phosphate-based electrolyte had a wide potential window within the-1 planarization efficiency and the Cu removal rate were great than 70% and 600 nm min , respectively,thus demonstrating its great potential as an electrolyte for electrochemical mechanical planarization.
机译:在这项工作中,系统研究了2-氨基-5-(乙硫基)-1,3,4-噻二唑(AETD)和氯离子-(Cl)在磷酸盐基电解质中的协同作用。 X射线光电子能谱仪的结果表明,确实将Cl掺入了含AETD的钝化膜中。-根据广泛的电化学和材料分析,掺有Cl的AETD钝化膜对铜阳极具有优异的耐腐蚀性由于形成致密的钝化膜,因此溶出度比单独的AETD钝化膜好。此外,磷酸盐基电解液中的AETD和Cl的组合在-1平面化效率内具有宽的电势窗口,并且Cu的去除率分别大于70%和600 nm min,从而证明了其作为电沉积的巨大潜力。用于电化学机械平面化的电解质。

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