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Influence of Plasma Treatment on Hydrogen Electrosorption Capacity by Carbon Electrodes

机译:等离子体处理对碳电极对氢电吸附能力的影响

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This paper is reports on the effect of plasma treatment with various discharge regimes and plasmasources (Ar, O2 and CO2) on hydrogen capacity of carbon electrodes. Among various modifications ofcarbon materials being undertaken to increase hydrogen storage capacity, plasma treatment seems tobe quite interesting one. Obtained results confirmed that surface properties modified by plasmatreatment play an important role in hydrogen electrosorption process. The highest hydrogen capacity,-1 i.e., 425 mAh g (1.56 wt.%) was recorded for electrode after 15 seconds of Ar-plasma treatment,whereas the lowest value was observed also for electrode after Ar-plasma treatment but with longertime, i.e., 300 seconds. The results for samples with O2 and CO2 plasma source are rather comparablewith the reference sample. Unfortunately, no direct dependency between plasma type, time oftreatment and hydrogen capacity was found, however, an repeatable increase of hydrogen stored on theelectrodes treated by Ar-plasma type was observed.
机译:本文报道了采用各种放电方式和等离子体源(Ar,O2和CO2)进行等离子体处理对碳电极氢容量的影响。在为了增加储氢能力而进行的各种碳材料修饰中,等离子体处理似乎是非常有趣的一种。所得结果证实,通过等离子体处理改性的表面性质在氢电吸附过程中起重要作用。氩气等离子体处理15秒后,电极的最高氢容量为-1,即425 mAh g(1.56 wt。%),而氩气等离子体处理后的电极也观察到了最低的氢容量,但时间更长,即,300秒。带有O2和CO2等离子体源的样品的结果与参考样品相当。不幸的是,没有发现等离子体类型,处理时间和氢容量之间的直接相关性,但是,观察到通过Ar-等离子体类型处理的电极上存储的氢可重复增加。

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