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Corrosion Inhibition of Steel in HCl by 2-Aminoethyl diphenylborinate

机译:2-氨基乙基二苯基硼酸酯对钢在HCl中的腐蚀抑制作用

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The corrosion behavior of C38 steel in HCl solution with different concentration of 2-Aminoethyldiphenylborinate C14H16BNO(DDB) was investigated by weight loss and electrochemical measurements.Results obtained reveal that DDB performs excellently as corrosion inhibitor for C38 steel in 1.0 M HCl.Potentiodynamic polarization studies have shown that DDB behaves as mixed-type inhibitors. Also, theinhibition efficiency was found to increase with increase of the inhibitor concentrations to reach 97.8 % at-3 2.10 M of DDB due to the adsorption of the inhibitor molecules on the metal surface and the adsorptionfollows Langmuir adsorption isotherm. EIS spectra exhibit one capacitive loop and confirm the inhibitiveability. Double layer capacitance and charge transfer resistance values were derived from Nyquist plotsobtained from impedance studies. Data obtained from EIS measurements, were analyzed to model thecorrosion inhibition process through appropriate equivalent circuit model; a constant phase element (CPE)has been used.
机译:通过失重和电化学测量,研究了C38钢在HCl溶液中的不同浓度的2-氨基乙基二苯基硼酸酯C14H16BNO(DDB)的腐蚀行为,结果表明DDB在1.0 M HCl中作为C38钢的缓蚀剂表现出色。已经表明DDB具有混合型抑制剂的作用。而且,发现由于抑制剂分子在金属表面上的吸附,并且随着Langmuir吸附等温线的吸附,随着抑制剂浓度的增加,在DDB-3-2.10M处抑制效率增加,达到97.8%。 EIS光谱显示出一个电容环,并确认了抑制性。双层电容和电荷转移电阻值来自阻抗研究获得的奈奎斯特图。分析从EIS测量获得的数据,以通过适当的等效电路模型对腐蚀抑制过程进行建模;使用了恒定相元件(CPE)。

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