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Corrosion Behavior of Aluminum Bronze under Thin Electrolyte Layers Containing Artificial Seawater

机译:含人工海水的电解质薄层下铝青铜的腐蚀行为

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The corrosion behavior of aluminum bronze under thin electrolyte layers (TELs) that contain artificialsea water has been investigated via Tafel polarization curve measurements, cathodic potentiodynamiccurve measurements, electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD),scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). Tafel polarizationcurve showed that the corrosion rate increased with decreasing TEL thickness at early stage, which isin good agreement with cathodic potentiodynamic curves and EIS measurements. However, afterimmersion for long periods of time, the corrosion rate varied non-monotonically with TEL thickness,at 302 m02 m03 mulk solution. The morphologies and EDS results demonstrated thataluminum bronze suffered a dealuminification corrosion and that the corrosion occurred initially at theinterface between the matrix and the phase, before developing further within the phase.
机译:通过Tafel极化曲线测量,阴极电位动力学曲线测量,电化学阻抗谱(EIS),X射线衍射(XRD),扫描电子显微镜(SEM)研究了铝青铜在含有人造海水的薄电解质层(TELs)下的腐蚀行为)和能量色散光谱(EDS)。 Tafel极化曲线表明,腐蚀速率在早期阶段随TEL厚度的减小而增加,这与阴极电势曲线和EIS测量值吻合良好。但是,长时间浸泡后,在302 m02 m03的浆液中,腐蚀速率随TEL厚度非单调变化。形态和EDS结果表明,铝青铜遭受了脱铝腐蚀,并且腐蚀最初发生在基体与相之间的界面处,然后在相中进一步发展。

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