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首页> 外文期刊>International Journal of Electrochemistry >Electrochemical Response of Platinum Ultrathin Layer Formed by Pulsed Laser Deposition
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Electrochemical Response of Platinum Ultrathin Layer Formed by Pulsed Laser Deposition

机译:脉冲激光沉积形成铂超薄层的电化学响应

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摘要

Ultrathin layer of platinum (ULPt) was deposited on glassy carbon (GC) substrate by using pulsed laser deposition (PLD) method, and electrochemical properties of the ULPt were discussed. The deposition was simply performed at room temperature with short deposition time. Atomic force microscopy and scanning electron microscopy images showed the flat surface of the ULPt. X-ray photoelectron spectroscopy (XPS) characterized the ULPt in the Pt(0) state, and biding energy of ULPt was positively shifted. These results indicated that nanostructure of Pt thin layer was formed. The electrochemical activity of the prepared ULPt on GC substrate was superior to a bulk Pt electrode regarding the potential and the magnitude of current on oxidizing hydrogen peroxide. This fast and easily prepared low-cost electrode had the potential to replace a conventional bulk metal electrode.
机译:采用脉冲激光沉积(PLD)方法在玻璃碳(GC)衬底上沉积了铂(ULPt)超薄层,并讨论了ULPt的电化学性能。简单地在室温下以短沉积时间进行沉积。原子力显微镜和扫描电子显微镜图像显示了ULPt的平坦表面。 X射线光电子能谱(XPS)表征了Pt(0)状态下的ULPt,并且ULPt的投标能量正向移动。这些结果表明形成了Pt薄层的纳米结构。就氧化过氧化氢的电势和电流大小而言,制备的ULPt在GC基质上的电化学活性优于大块Pt电极。这种快速且容易制备的低成本电极具有取代常规块状金属电极的潜力。

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