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Solubility and absorption rate of CO 2 in MEA in the presence of graphene oxide nanoparticle and sodium dodecyl sulfate

机译:氧化石墨烯纳米颗粒和十二烷基硫酸钠存在下CO 2 在MEA中的溶解度和吸收率

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The aim of this work is to find the effect of the adding graphene oxide nanoparticle ands dodecyl sulfate (SDS) on the absorption rate and solubility of CO~(2)in mono-ethanolamine (MEA) solvent. To this end, an experimental setup was designed and constructed to measure the gas solubility in the solvent and the absorption rate during the process. The experiments were conducted at ambient temperature and initial pressure of 20?bar. The parameters analyzed in this paper included GO-NPS at 0.0375, 0.05, 0.075 and 0.1%, SDS at the same percentages, and the simultaneous effects of both additives. In each experiment, the absorption rate and solubility were calculated by recording the temperature and pressure variations in the absorption and loading chambers. The results indicated that the highest effect of GO-NPS was in the concentration of 0.05%, increasing solubility by up to 7.62%. These values for SDS were 0.075% and 8.39%, respectively. In the experiment with both additives at 0.05% and 0.075% for GO-NPS and SDS, solubility increased by 6.32% and simultaneous presence of both compounds had the greatest effect on absorption rate. Comparison of the results of mole variations suggested that addition of nanoparticles and surfactants both increased the absorption rate.
机译:这项工作的目的是发现添加氧化石墨烯纳米颗粒和十二烷基硫酸盐(SDS)对CO〜(2)在单乙醇胺(MEA)溶剂中的吸收速率和溶解度的影响。为此,设计并构建了一个实验装置,以测量该溶剂在溶剂中的气体溶解度以及在此过程中的吸收速率。实验是在环境温度和20巴的初始压力下进行的。本文分析的参数包括:GO-NPS分别为0.0375、0.05、0.075和0.1%,SDS的百分数相同,并且两种添加剂的同时作用。在每个实验中,通过记录吸收室和加载室中的温度和压力变化来计算吸收率和溶解度。结果表明,GO-NPS的最大作用是浓度为0.05%,溶解度提高了7.62%。 SDS的这些值分别为0.075%和8.39%。在GO-NPS和SDS的添加量分别为0.05%和0.075%的实验中,溶解度提高了6.32%,并且两种化合物同时存在对吸收率的影响最大。摩尔变化结果的比较表明,添加纳米颗粒和表面活性剂均增加了吸收速率。

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