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Modified Desalination Scheme for Handling Reject Brines

机译:修改后的脱盐方案来处理盐水

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The main goal of this work is to present a sustainable modified desalination scheme which incorporates a chemical conversion unit (CCU) that handles the reject brines exit the desalination unit. With the available technology, we have today this can change the paradigm of “##waste product”## into a “##resource”## aiming for the utilization of brine, as a feed stock for magnesium production plus other chemical products to take place. It is a chemical process that involves bubbling CO2 gas in “##ammoniated”## brine. The brine used contains about 25% NaCl and is obtained by concentrating the reject brine before entering the CCU. The proposed method, offers a vehicle to dispose reject brine and to utilize it, at the same time, to recover and extract valuable minerals found in these rejects. In the proposed method, ammonia used in the chemical conversion process is synthesized by using renewable hydrogen, obtained by water electrolysis. A preliminary process analysis of the proposed system is presented along with computational results. For one cubic meter of reject brine, 0.64 ton ammonium chloride (found in partially desalinated water) and 0.63 ton soda ash are produced, while 0.203 ton ammonia and 0.526 ton carbon dioxide are consumed. In addition, the recovery of MgCl2 from reject brine adds merits to the proposal.
机译:这项工作的主要目的是提出一种可持续的改进型脱盐方案,该方案包括一个化学转化装置(CCU),用于处理从脱盐装置排出的废盐水。借助现有技术,我们今天可以将“#8220#废物产品”的范例转变为旨在利用盐水作为镁原料的“#8220 ## resource”和“#8221 ##”。生产以及其他化学产品的生产。这是一个化学过程,涉及在氨化的盐水中鼓泡CO2气体。所使用的盐水包含约25%NaCl,可通过在进入CCU之前浓缩废盐水来获得。所提出的方法提供了一种处置残渣盐水并同时利用它来回收和提取在这些残渣中发现的有价值的矿物的工具。在提出的方法中,化学转化过程中使用的氨是通过使用水电解得到的可再生氢合成的。提出系统的初步过程分析以及计算结果。对于一立方米的废盐水,将产生0.64吨氯化铵(存在于部分淡化水中)和0.63吨苏打灰,而消耗了0.203吨氨和0.526吨二氧化碳。此外,从废盐水中回收MgCl2的建议也有所增加。

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