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Activities of FexO in Molten Slags Coexisting with Solid CaO and Ca2SiO4–Ca3P2O8 Solid Solution

机译:Fe x O在固态CaO和Ca 2 SiO 4 –Ca 3 P < sub> 2 O 8 固溶体

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In steelmaking processes, there are incentives to reduce slag volume and CaO consumption. The key to meet these requirements is the better understanding of CaO dissolution mechanism into molten slag, which relies on the knowledge of the thermochemical properties of slags and fluxes used for dephosphorization. In this study, the liquidus compositions coexisted with solid CaO and Ca_(2)SiO_(4)–Ca_(3)P_(2)O_(8) solid solution simultaneously were determined in the quaternary system CaO–SiO_(2)–P_(2)O_(5)–Fe_(x)O at 1573 K. Measurements were also conducted on the Fe_(x)O activities at temperatures between 1542 K and 1604 K by virtue of an electrochemical technique. By using the present experimental results, phosphorus distribution ratios were estimated.
机译:在炼钢过程中,存在减少炉渣量和减少CaO消耗的诱因。满足这些要求的关键是更好地了解CaO在熔融炉渣中的溶解机理,这取决于对炉渣的热化学性质和用于脱磷的助熔剂的了解。在这项研究中,在四元体系CaO–SiO_(2)–P_中同时测定了固相CaO和Ca_(2)SiO_(4)–Ca_(3)P_(2)O_(8)固溶体共存的液相线成分。 (2)O_(5)–Fe_(x)O在1573K。还通过电化学技术对在1542 K和1604 K之间的温度下的Fe_(x)O活性进行了测量。通过使用目前的实验结果,可以估算磷的分配比例。

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