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Beneficiation of High Phosphorus Limonite Ore by Sodium-carbonate-added Carbothermic Reduction

机译:碳酸钠加碳热还原法精制高磷褐铁矿

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The characteristics of Huimin high phosphorus limonite ore and the beneficiation of this iron ore by sodium-carbonate-added carbothermic reduction, ultrafine grinding and magnetic separation were investigated. Iron particle size in reduced ore without Na_(2)CO_(3) additive is tiny and the fayalite is abundant. It is indicated that the formation of fayalite is the main hindrance to accelerate the reduction of limonite. With a mass ratio of Na_(2)O_(3) to ore of 10% additive, the reduction of limonite can be reinforced. The reinforcing affect may be caused by the increase of the reducing reaction activity of FeO and the acceleration of the carbon gasification reaction rate. Fluorapatite were not reduced in the low temperature reduction process and entered to gangue phases, after ultrafine grinding-magnetic separation process, a qualified iron concentrate with 76.47% Fe, a recovery of 73.20% is obtained with simultaneous decrease in the phosphorus content down to 0.25%.
机译:研究了惠民高磷褐铁矿的特性,并通过碳酸钠加碳热还原,超细粉碎和磁选对该铁矿石进行了选矿。没有添加Na_(2)CO_(3)的还原矿石中的铁粒度很小,铁橄榄石含量丰富。结果表明,铁橄榄石的形成是促进褐铁矿还原的主要障碍。通过Na_(2)O_(3)与矿石的质量比为10%的添加剂,可以增强褐铁矿的还原性。 FeO的还原反应活性的增加和碳气化反应速度的加快可能引起增强作用。氟磷灰石在低温还原过程中未还原,进入脉石阶段,经过超细研磨-磁选过程,得到合格的铁精矿,含铁量为76.47%,回收率为73.20%,同时磷含量降低至0.25。 %。

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