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Comparison of Fe, Zn, Mn, Cu, Cd and Pb concentration in spruce needles collected in the area of Gdansk and Gdynia in Northern Poland

机译:波兰北部格但斯克和格丁尼亚地区收集的云杉针中铁,锌,锰,铜,镉和铅的浓度比较

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The aim of the investigation was to assess the utility of spruce needles as a potential material to be used for monitoring the contamination level of the environment of Tricity agglomeration (represented by Gdansk and Gdynia). This aim was realized by determining the levels of selected essential elements indispensable for the life of living organisms, such as Fe, Zn, Mn and Cu, as well as toxic, namely Cd and Pb, in spruce needles collected in the locations in Gdynia and for comparison, in Gdańsk. Due to this, the collected samples of needles were dried, and next digested by microwave technique in order to prepare them for quantitative analysis by atomic absorption spectrometry. Moreover, the same metallic elements were determined in the soil samples collected under the spruces, from which needles were taken for the investigation. The concentrations of the studied elements were found in the range of mg/kg of dry mass in the following order: Fe, Mn, Zn, Pb, Cu and Cd (needles), and Fe, Mn, Cu, Zn, Pb and Cd (soils). By application of statistical methods (correlation, variance and principal component analyses), the differences in the elemental composition of spruce needles were identified, as well as sources of this differentiation.
机译:该调查的目的是评估云杉针头作为一种潜在材料的实用性,该材料可用于监视Tricity集聚环境的污染程度(由格但斯克和格丁尼亚代表)。通过确定在格丁尼亚州和格丁尼亚州收集的云杉针头中对某些生物必需的必需元素(如铁,锌,锰和铜)以及有毒物质(镉和铅)的水平,从而实现了该目标。作为比较,在格但斯克。因此,将收集到的针状样品干燥,然后通过微波技术进行消解,以准备通过原子吸收光谱法进行定量分析。此外,在云杉下收集的土壤样品中确定了相同的金属元素,并从中取出针进行调查。所研究元素的浓度按以下顺序在干燥质量的mg / kg范围内:Fe,Mn,Zn,Pb,Cu和Cd(针)以及Fe,Mn,Cu,Zn,Pb和Cd (土壤)。通过应用统计方法(相关性,方差和主成分分析),可以识别云杉针的元素组成的差异以及这种差异的来源。

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