Purple of Cassius: Nano Gold or Colloidal Gold?

Fathi Habashi

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Purple of Cassius: Nano Gold or Colloidal Gold?

机译：卡修斯的紫色：纳米金还是胶体金？

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The purple pigment that is used in colouring molten glass and porcelain known as Purple of Cassius discovered in the 17 th century was found by Richard Zsigmondy in 1897 to consist of nano gold with stannic oxide. The preparation of this material involves gold being dissolved in aqua regia , then reacted with a solution of tin(II) chloride. The tin(II) chloride reduces the dissolved gold to elemental gold supported on tin dioxide to give a purple precipitate which is thermally stable and is used as a pigment to give purple colour to glass and porcelain.

机译：理查德·西格蒙迪（Richard Zsigmondy）于1897年发现了一种紫色颜料，用于为熔融玻璃和瓷器上色，被称为卡修斯紫色（Cassius），该颜料于1897年由纳米金和氧化锡组成。该材料的制备涉及将金溶解在王水中，然后与氯化锡（II）溶液反应。氯化锡（II）将溶解的金还原为负载在二氧化锡上的元素金，得到紫色沉淀，该沉淀具有热稳定性，并用作颜料使玻璃和瓷器具有紫色。

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《European Chemical Bulletin》 |2016年第10期|共4页
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Fathi Habashi;
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Purple of Cassius: Nano Gold or Colloidal Gold?

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