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首页> 外文期刊>Revista Brasileira de Fruticultura >Residues of carbosulfan and its carbofuran metabolites and 3-hydroxy-carbofuran in oranges
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Residues of carbosulfan and its carbofuran metabolites and 3-hydroxy-carbofuran in oranges

机译:桔子中硫丹及其碳呋喃代谢产物和3-羟基碳呋喃的残留量

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The objectives of this study were to evaluate the residues of the insecticide carbosulfan and its carbofuran metabolites and 3-hydroxy-carbofuran in orange compartments (whole fruit, bagasse and juice) and comparison between the residual levels found in fruits with the maximum residue level and the safety interval established by the Brazilian legislation. Two field experiments were carried out, both with the following treatments: a-check; b-one application of 10 g of carbosulfan . 100 L-1 of water; c-one application with twice the rate applied in treatment b; d-four applications with the same rate applied in treatment b. Samples were taken at (-1), zero, 1, 3, 7, 14, 21 and 28 days after the last or unique application. The quantitative determinations were done by gas chromatography technique, using a nitrogen-phosphorus detector. The carbosulfan metabolism to its carbofuran metabolite was rapid (3 days), being both analytes concentrated in the bagasse (peel + flavedo + albedo). However, the metabolism of carbofuran to 3-hydroxy-carbofuran was of low intensity or this metabolite was quickly dissipated. Carbosulfan residues and its metabolites did not penetrate into the fruit, thus not contaminating the juice. The use of the pesticide was adequate, with respect to fruit consumption, in relation to the Brazilian legislation.
机译:这项研究的目的是评估橙色隔室(整个水果,甘蔗渣和果汁)中杀虫剂硫丹及其碳氢呋喃代谢物和3-羟基碳呋喃的残留量,并比较最大残留量和最大残留量的果实中的残留量。巴西法律规定的安全间隔。进行了两个野外实验,均经过以下处理:a-检查; b-一次施用10 g的硫丹。 100 L-1的水; c-一次施用,其速率是治疗b的两倍; d-在治疗中以相同的比率进行四次施用b。在最后一次或唯一应用后的(-1),零,1、3、7、14、21和28天取样。使用氮磷检测器通过气相色谱技术进行定量测定。 Carbosulfan代谢成Carbofuran代谢物的速度很快(3天),因为两种分析物都浓缩在甘蔗渣中(果皮+ flavedo +反照率)。但是,呋喃丹向3-羟基-卡呋喃的代谢强度很低,或者这种代谢物很快消失了。硫丹残留及其代谢物不会渗透到水果中,因此不会污染果汁。就巴西的立法而言,就水果消费而言,农药的使用是足够的。

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