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首页> 外文期刊>Polymer Sciences >Fabrication and Characterization of New Unsaturated Terpolyesters Based on Diarylidenecyclohexanone
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Fabrication and Characterization of New Unsaturated Terpolyesters Based on Diarylidenecyclohexanone

机译：基于二芳基亚环己酮的新型不饱和三元聚酯的制备与表征

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摘要

In the present study new unsaturated terpolyesters based on diarylidenecyclohexanone, were synthesized by the interfacial polycondensation polymerization technique. Aldol condensation reaction in acid media was used for preparation of three kinds of monomers and investigated by FT IR and 1H NMR as discussed in our resent work. The terpolymers were synthetized by the polymerization of 2,6-bis (4-hydrxybenzylidene) cyclohexanone I, 2,6-bis (3-hydroxybezylidene) cyclohexanone II, and 2,6-bis (4-hydroxy-3- methoxybenzylidene) cyclohexanone III with isophthaloyl, terphthaloyl, adipoyl, sebacoyl and azobenzene 4,4-dicaroxyldichloride. The resulting terpolyesters were characterized by FT-IR, 1HNMR. The molecular weight was determined by the intrinsic viscosity measurements. The thermal stabilities of the prepared Terpolyester were evaluated thermogravimeteric analysis (TGA). Differential thermal analysis (DTA) was used for determination of glass temperatures. X-ray analysis shows the degree of crystallinity. The morphological properties of some selected polymers were detected by SEM.
机译：在本研究中，通过界面缩聚聚合技术合成了基于二亚芳基环己酮的新型不饱和三元聚酯。酸性介质中的醛醇缩合反应用于制备三种单体，并通过FT IR和1H NMR进行了研究，这在我们的近期工作中已有讨论。通过聚合2,6-双（4-羟基亚苄基）环己酮I，2,6-双（3-羟基亚苄基）环己酮II和2,6-双（4-羟基-3-甲氧基亚苄基）环己酮来合成三元共聚物III与间苯二甲酰，对苯二甲酰，己二酰，癸二酰和偶氮苯4，4-二氧二氯二氯。所得三元聚酯通过FT-IR，1 HNMR表征。通过特性粘度测量确定分子量。对制备的三元聚酯的热稳定性进行热重分析（TGA）。差热分析（​​DTA）用于确定玻璃温度。 X射线分析显示结晶度。通过扫描电镜（SEM）检测了部分聚合物的形貌。

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