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Recent Advances in Boron-Containing Conjugated Porous Polymers

机译:含硼共轭多孔聚合物的最新进展

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Porous polymers, integrating the advantages of porous materials and conventional polymers, have been well developed and exhibited tremendous attention in the fields of material, chemistry and biology. Of these, boron-containing conjugated porous polymers, featuring tunable geometric structures, unique Lewis acid boron centers and very rich physical properties, such as high specific surface, chargeable scaffold, strong photoluminescence and intramolecular charge transfer, have emerged as one of the most promising functional materials for optoelectronics, catalysis and sensing, etc. Furthermore, upon thermal treatment, some of them can be effectively converted to boron-doped porous carbon materials with good electrochemical performance in energy storage and conversion, extensively enlarging the applicable scope of such kinds of polymers. In this review, the synthetic approaches, structure analyses and various applications of the boron-containing conjugated porous polymers reported very recently are summarized.
机译:结合了多孔材料和常规聚合物优点的多孔聚合物已经得到了很好的开发,并在材料,化学和生物学领域表现出极大的关注。其中,具有可调几何结构,独特的路易斯酸硼中心和非常丰富的物理特性(例如高比表面,带电支架,强光致发光和分子内电荷转移)的含硼共轭多孔聚合物已成为最有前途的技术之一此外,通过热处理,它们中的一些可以有效地转化为掺硼的多孔碳材料,在储能和转化方面具有良好的电化学性能,从而大大扩大了这类材料的适用范围。聚合物。在这篇综述中,总结了最近报道的含硼共轭多孔聚合物的合成方法,结构分析和各种应用。

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