首页> 外文期刊>Polymers >Poly(3,3-dibenzyl-3,4-dihydro-2 H -thieno[3,4- b ][1,4]dioxepine)/Platinum Composite Films as Potential Counter Electrodes for Dye-Sensitized Solar Cells
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Poly(3,3-dibenzyl-3,4-dihydro-2 H -thieno[3,4- b ][1,4]dioxepine)/Platinum Composite Films as Potential Counter Electrodes for Dye-Sensitized Solar Cells

机译:聚(3,3-二苄基-3,4-二氢-2 H-噻吩并[3,4- b] [1,4]二氧杂环丁烷)/铂复合膜作为染料敏化太阳能电池的潜在对电极

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In this study, poly(3,3-dibenzyl-3,4-dihydro-2 H -thieno[3,4- b ][1,4]dioxepine)/platinum composite films (PProDOT-Bz 2 /Pt) were used as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). The composite films were prepared on fluorine-doped tin oxide (FTO) glass by radio frequency (RF) sputtering to deposit platinum (Pt) for 30 s. Afterwards, PProDOT-Bz 2 was deposited on the Pt–FTO glass via electrochemical polymerization. The electron transfer process of DSSCs was investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The DSSCs with 0.05 C/cm 2 PProDOT-Bz 2 -Pt composite films showed an open circuit voltage ( V oc ) of 0.70 V, a short-circuit current density ( J sc ) of 7.27 mA/cm 2 , and a fill factor (F.F.) of 68.74%. This corresponded to a photovoltaic conversion efficiency (η) of 3.50% under a light intensity of 100 mW/cm 2 .
机译:在这项研究中,使用了聚(3,3-二苄基-3,4-二氢-2 H-噻吩并[3,4-b] [1,4]二氧杂环丁烷)/铂复合膜(PProDOT-Bz 2 / Pt)作为染料敏化太阳能电池(DSSC)中的对电极(CE)。通过射频(RF)溅射在氟掺杂氧化锡(FTO)玻璃上制备复合膜,以沉积铂(Pt)30 s。之后,通过电化学聚合将PProDOT-Bz 2沉积在Pt-FTO玻璃上。使用电化学阻抗谱(EIS)和循环伏安法(CV)研究了DSSC的电子转移过程。具有0.05 C / cm 2 PProDOT-Bz 2 -Pt复合膜的DSSC显示的开路电压(V oc)为0.70 V,短路电流密度(J sc)为7.27 mA / cm 2,并且填充系数(FF)为68.74%。这对应于在100mW / cm 2的光强度下的光电转换效率(η)为3.50%。

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