Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols

Arlene G. Corrêa; Julia L. Monteiro; Márcio W. Paix?o; Rodrigo César Da Silva; Senthil Narayanaperumal

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Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols

机译：氯化铁（III）催化过酰基化糖与烯丙/炔醇的糖基化

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In this work, the use of ferric chloride as an efficient catalyst in glycosylation reactions of sugars in the presence of allyl and alkynyl alcohols is described. The corresponding glycosides were obtained with moderate to good yields. This new procedure presented greater selectivity when compared to classic methods found in the literature. Principal features of this simple method include non-hazardous reaction conditions, low-catalyst loading, good yields and high anomeric selectivity.

机译：在这项工作中，描述了在烯丙基和炔醇存在下，氯化铁作为糖的糖基化反应中的有效催化剂的用途。以中等至良好的产率获得了相应的糖苷。与文献中的经典方法相比，这种新方法具有更高的选择性。这种简单方法的主要特征包括无危险的反应条件，低催化剂负载，高收率和高异头异构体选择性。

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《Journal of the Brazilian Chemical Society》 |2012年第11期|共7页
作者
Arlene G. Corrêa; Julia L. Monteiro; Márcio W. Paix?o; Rodrigo César Da Silva; Senthil Narayanaperumal;
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中图分类生物物理学;
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1. Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols [J] . Narayanaperumal S., Da Silva R.C., Monteiro J.L., Journal of the Brazilian Chemical Society . 2012,第11期

机译：氯化铁（III）催化过酰基化糖与烯丙/炔醇的糖基化
2. Iron(III) chloride-catalyzed synthesis of 3-carboxy-2,5-disubstituted furans from gamma-alkynyl aryl- and alkylketones [J] . Golonka Alexander N., Schindler Corinna S. Tetrahedron . 2017,第29期

机译：氯化铁（III）氯化物催化合成来自γ-炔基芳基和烷基芳基的3-羧基-2,5-二取代的呋喃
3. Iron(III) Chloride/Phenylsilane-Mediated Cascade Reaction of Allyl Alcohols with Maleimides: Synthesis of Poly-Substituted gamma-Butyrolactones [J] . Zhang Hua, Zhan Xiao-Yu, Chen Xu-Ling, Advanced synthesis & catalysis . 2019,第21期

机译：铁（III）氯化物/苯硅烷介导的烯丙基醇与马来酰亚胺的级联反应：聚取代γ-丁内酯的合成
4. Effective Hydroalkoxylation/Cyclization of Alkynyl Alcohol Catalyzed by ln(OTf)_3 [C] . ZHANG Jian-Ting, ZHU Cheng-Lin, FENG Jun-Min International Conference on Chemical Engineering and Advanced Materials . 2014

机译：用LN（OTF）_3催化催化的炔基醇的有效的水烷氧基化/环化
5. Palladium-catalyzed carboxylative coupling reactions of allyltributylstannanes and allyl chloride. [D] . Franks, Russell James. 2002

机译：烯丙基三丁基锡与烯丙基氯的钯催化的羧基偶联反应。
6. Iron(III) chloride-catalyzed activation of glycosyl chlorides [O] . Scott A. Geringer, Alexei V. Demchenko -1

机译：氯化铁（III）催化糖基氯化物的活化
7. Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols [O] . Senthil Narayanaperumal, Rodrigo César da Silva, Julia L. Monteiro, 2012

机译：铁（III）氯化物用烯丙基/炔基醇催化过苯基化糖的糖基化

Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols

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