Synthesis of N,O-Type Inherently Chiral Calix[4]arenes Substituted on the Lower Rim and their Organocatalysis Properties

Chang Ming-Liang; He Yong; Zhou Jing; Li Shao-Yong

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Synthesis of N,O-Type Inherently Chiral Calix[4]arenes Substituted on the Lower Rim and their Organocatalysis Properties

机译：N，O型固有手性杯[4]芳烃取代低级环的合成及其有机催化性能

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>This work presented the first study of organocatalytic behaviors of inherently chiral calix[4]arenes substituted at the lower rim. A pair of N, O-type enantiomers based on inherently chiral calix[4]arenes substituted at the lower rim were readily synthesized and applied to catalyze Henry reaction between aromatic aldehydes and nitromethane. Their organocatalytic reaction can afford the desired products in excellent yields (up to 99%) but poor enantioselectivities (up to 7.5% ee).

机译：>这项工作是对固有手性杯[4]芳烃在下边缘取代的有机催化行为的首次研究。一对容易合成的基于固有手性杯[4]芳烃的N，O型对映异构体在下边缘被取代，并被用于催化芳香醛和硝基甲烷之间的亨利反应。它们的有机催化反应可以以优异的产率（高达99％）提供所需的产物，但对映选择性差（高达7.5 ee）。

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《Journal of the Brazilian Chemical Society》 |2017年第8期|共8页
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Chang Ming-Liang; He Yong; Zhou Jing; Li Shao-Yong;
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中图分类生物物理学;
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1. Synthesis of N,O -Type Inherently Chiral Calix[4]arenes Substituted on the Lower Rim and their Organocatalysis Properties [J] . Shao-Yong Li, Yong He, Ming-Liang Chang, Journal of the Brazilian Chemical Society . 2017,第8期

机译：N，O型固有手性杯[4]芳烃取代低级环的合成及其有机催化性能
2. Resolution of inherently chiral calix[4]arenes with AABB and CDCD substitution patterns on the upper and lower rims, respectively [J] . Caccamese S., Cunsolo F., Parlato S., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2000,第15期

机译：分别在上，下轮缘上使用AABB和CDCD取代模式拆分固有手性杯[4]芳烃
3. Synthesis of inherently chiral wide rim ABC substituted calix[6]arene derivatives [J] . Liu J.-M., Shi J.-Y., Xu Y.-W., Supramolecular chemistry . 2011,第5a6期

机译：固有手性宽边ABC取代杯[6]芳烃衍生物的合成
4. Calix4arenes with a Lid in their Upper Rims: 1,3-Dipolar Cycloaddition Reactions of Benzonitrile Oxides with 5-Allyl-, 5,11- Diallyl- and 5,17-Dialiylcalix4arenes [C] . Wen-Sheng Chung International symposium for Chinese organic chemists . 2000

机译：Calix 4在其上轮辋中盖子：用5-烯丙基，5,11-二烯丙基和5,17-二烷基丙烯酰胺的1,3-偶极环加成反应4
5. Synthesis of Bridged Calix[4]arenes by Selective Functionalization at the Lower Rim and Synthesis of Block Copolymers Containing Poly(3-hexylthiophene). [D] . Hailu, Shimelis T. 2012

机译：通过在较低的边缘选择性官能化合成桥接的杯[4]芳烃和合成含聚（3-己基噻吩）的嵌段共聚物。
6. Correction: Inherently chiral calix4arenes via oxazoline directed ortholithiation: synthesis and probe of chiral space [O] . Simon A Herbert, Laura J van Laeren, Dominic C Castell, 2017

机译：校正：通过恶唑啉定向原石化固有地手性杯4芳烃：手性空间的合成和探测
7. Diastereoselective Lower Rim (1S)-Camphorsulfonylation as the Shortest Way to the Inherently Chiral Calix4arene [O] . -1

机译：Dia对映选择性的下轮辋（1S） - Camphorsulfonation作为固有的手性胶囊的最短方法4芳烃

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Synthesis of N,O-Type Inherently Chiral Calix[4]arenes Substituted on the Lower Rim and their Organocatalysis Properties

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