Crystal structure of 12-benzyl­sulfanyl-2,9-di­bromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one

Resch S.; Quell T.; Schollmeyer D.; Waldvogel S.R.

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Crystal structure of 12-benzylsulfanyl-2,9-dibromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one

机译：12-苄基硫烷基-2,9-二溴-6H-二苯并[b，g] [1,8]萘啶-11-一的晶体结构

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The heterotetracene skeleton of the title molecule, C23H14Br2N2OS, is defined by linear annulation of four six-membered rings, including two N heteroatoms. This moiety is nearly planar (r.m.s. deviation = 0.055 Å), with a slight twist of 4.1 (2)° between the two halves of the aromatic system. The dihedral angle between the least-squares plane of the skeleton and the benzyl group is 24.5 (3)°; the C—S—C angle involving the benzylsulfanyl group is 99.2 (4)°. In the crystal, molecules are π-stacked in an antiparallel fashion along [110], with a distance between the aromatic planes of 3.47 (2) Å. Intermolecular N—H⋯O hydrogen bonds form chains extending parallel to [001] and bridge the antiparallel interdigitated stacks of molecules.

机译：标题分子C23H14Br2N2OS的异并四烯骨架是由四个六元环（包括两个N杂原子）的线性环状定义的。该部分几乎是平面的（r.m.s.偏差= 0.055Å），在芳族体系的两半之间略有4.1（2）°的扭曲。骨架的最小二乘法面与苄基的二面角为24.5°（3）°。涉及苄硫基的CS角为99.2°（4）°。在晶体中，分子沿[110]以反平行的方式π堆积，芳香平面之间的距离为3.47（2）Å。分子间NH 3 O氢键形成平行于[001]延伸的链并桥接反平行的叉指状分子堆叠。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第9期|共页
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Resch S.; Quell T.; Schollmeyer D.; Waldvogel S.R.;
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中图分类晶体学;
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CRYSTAL STRUCTURE1,8-NAPHTHYRIDINEHETEROTETRACENE;

机译：晶体结构1,8-萘啶异戊烯;

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1. Crystal structure of 12-benzylsulfanyl-2,9-dibromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one [J] . Resch S., Quell T., Schollmeyer D., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

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Crystal structure of 12-benzyl­sulfanyl-2,9-di­bromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one

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Crystal structure of 12-benzylsulfanyl-2,9-dibromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one