...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of a new hybrid compound based on an iodido-plumbate(II) anionic motif
【24h】

Crystal structure of a new hybrid compound based on an iodido-plumbate(II) anionic motif

机译：基于碘-铅酸（II）阴离子基序的新型杂化化合物的晶体结构

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Crystals of the one-dimensional organic–inorganic lead iodide-based compound catena-poly[bis-(piperazine-1,4-diium) [[tetra-iodido-plumbate(II)]-μ-iodido] iodide monohydrate], (C4N2H12)2[PbI5]I·H2O, were obtained by slow evaporation at room temperature of a solution containing lead iodide and piperazine in a 1:2 molar ratio. Inorganic lead iodide chains, organic (C4N2H12)2+ cations, water mol-ecules of crystallization and isolated I? anions are connected through N—H?·I, N—H?OW and OW—H?I hydrogen-bond inter-actions. Zigzag chains of corner-sharing [PbI6]4? octa-hedra with composition [PbI4/1I2/2]3? running parallel to the a axis are present in the structure packing.
机译：一维有机-无机碘化铅基化合物catena-poly [bis-（piperazine-1,4-diium）[[tetra-iodido-plumbate（II）]-μ-iodido] iodide一水合物]的晶体，（ C4N2H12）2 [PbI5] I·H2O是通过在室温下缓慢蒸发含有碘化铅和哌嗪的摩尔比为1：2的溶液而获得的。无机碘化铅链，有机（C4N2H12）2+阳离子，结晶水分子和分离出的I？阴离子通过NH-I，NH-OW和OW-HI氢键相互作用连接。共享的[PbI6] 4之字形链？组成为[PbI4 / 1I2 / 2] 3的八面体。结构填料中存在平行于a轴的方向。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号