Synthesis and crystal structure of Na4Ni7(AsO4)6

David R.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Synthesis and crystal structure of Na4Ni7(AsO4)6

【24h】

Synthesis and crystal structure of Na4Ni7(AsO4)6

机译：Na4Ni7（AsO4）6的合成与晶体结构

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The title compound, tetrasodium heptanickel hexaarsenate, was obtained by ceramic synthesis and crystallizes in the monoclinic space group C2/m. The asymmetric unit contains seven Ni atoms of which two have site symmetry 2/m and three site symmetry 2, four As atoms of which two have site symmetry m and two site symmetry 2, three Na atoms of which two have site symmetry 2, and fifteen O atoms of which four have site symmetry m. The structure of Na4Ni7(AsO4)6 is made of layers of Ni octahedra and As tetrahedra assembled in sheets parallel to the bc plane. These layers are interconnected by corner-sharing between NiO6 octahedra and AsO4 tetrahedra. This linkage creates tunnels running along the c axis in which the Na atoms are located. This arrangement is similar to the one observed in Na4Ni7(PO4)6, but the layers of the two compounds are slightly different because of the disorder of one of the Ni sites in the structure of the title compound.

机译：通过陶瓷合成获得标题化合物庚锡六砷酸四钠，并在单斜空间群C2 / m中结晶。该不对称单元包含七个Ni原子，其中两个具有位对称2 / m和三个位对称2，四个As原子，其中两个具有位对称m和两个位对称2，三个Na原子，其中两个具有位对称2，和15个O原子，其中4个具有位对称m。 Na 4 Ni 7（AsO 4）6的结构是由八面体Ni和四面体As组成，它们平行于bc平面成片状组装。这些层通过NiO6八面体和AsO4四面体之间的角共享而互连。这种联系形成了沿Na原子所在的c轴延伸的隧道。这种排列方式类似于在Na4Ni7（PO4）6中观察到的排列方式，但是由于标题化合物结构中Ni位置之一的无序，两种化合物的层略有不同。

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第5期|共3页
作者
David R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Crystal chemistry of anhydrous Li uranyl phosphates and arsenates. I. Polymorphism and structure topology: Synthesis and crystal structures of alpha-Li[(UO2)(PO4)], alpha-Li[(UO2)(AsO4)], beta-Li[(UO2)(AsO4)] and Li-2[(UO2)(3)(P2O7)(2)] [J] . Alekseev EV, Krivovichev SV, Malcherek T, Journal of Solid State Chemistry . 2008,第11期

机译：无水磷酸锂铀酰和砷酸的晶体化学。 I.多态性和结构拓扑：α-Li[（UO2）（PO4）]，α-Li[（UO2）（AsO4）]，β-Li[（UO2）（AsO4）]和Li-的合成和晶体结构2 [（UO2）（3）（P2O7）（2）]
2. Mild hydrothermal synthesis, crystal structure, thermal behavior, spectroscopic and magnetic properties of the (NH4)[Fe(AsO4)(1-x)(PO4)(x)F] (x=0.3, 0.6, 0.8) series. Thermal transformation of (NH4)[Fe(AsO4)(0.7)(PO4)(0.3)F] into the textural porous orthorhombic Fe(AsO4)(0.7)(PO4)(0.3) [J] . Berrocal Teresa, Mesa Jose L., Pizarro Jose L., Journal of Solid State Chemistry . 2009,第4期

机译：（NH4）[Fe（AsO4）（1-x）（PO4）（x）F]（x = 0.3，0.6，0.8）系列的轻度水热合成，晶体结构，热行为，光谱和磁性能。（NH4）[Fe（AsO4）（0.7）（PO4）（0.3）F]的热转变为多孔质正交晶Fe（AsO4）（0.7）（PO4）（0.3）
3. Synthesis, crystal structure, infrared and Raman spectra of Sr4Cu3(AsO4)2(AsO3OH)4·3H2O and Ba2Cu4(AsO4)2(AsO3OH)3 [J] . Tamara Dordevic, Ljiljana Karanovic International Journal of Quantum Chemistry . 2008,第11期

机译：Sr4Cu3（AsO4）2（AsO3OH）4·3H2O和Ba2Cu4（AsO4）2（AsO3OH）3的合成，晶体结构，红外光谱和拉曼光谱
4. The Synthesis and Crystallography of Some Novel ZnO Nano- and Micro- Crystals and Structures [C] . Zongmu LI, Faqiang XU, Wenhua ZHANG International Conference on Materials for Advanced Technologies . 2008

机译：一些新型ZnO纳米和微晶和结构的合成与结晶学
5. Synthesis of doped semiconductor nanostructures using microemulsions and liquid crystals as templates. [D] . Panzarella, Tracy Heckler. 2010

机译：使用微乳液和液晶为模板合成掺杂的半导体纳米结构。
6. Synthesis and crystal structure of Na4Ni7(AsO4)6 [O] . Rénald David 2016

机译：Na4Ni7（AsO4）6的合成与晶体结构
7. Synthesis and crystal structure of Na4Ni7(AsO4)6 [O] . Rénald David 2016

机译：Na4Ni7（asO4）6的合成和晶体结构
8. 1. Innovative Relaxor-Based PiezoCrystals: Phase Diagrams, Crystal Growth, Domain Structures and Electric Properties. 2. Piezo- and Ferroelectric Materials Based on Morphotropic Phase Boundary Synthesis, Characterization and Structure - Property Relations [R] . Ye, Z. G. 2006

机译：1.创新的基于弛豫的压电晶体：相图，晶体生长，畴结构和电性质。基于准同型相界合成，表征和结构 - 性质关系的压电和铁电材料

Synthesis and crystal structure of Na4Ni7(AsO4)6

摘要

著录项

相似文献

相关主题

期刊订阅