Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ4O,O′:O′′,O′′′}cobalt(II)]

Xie C.; Zheng C.G.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O,O′:O′′,O′′′}cobalt(II)]

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Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O,O′:O′′,O′′′}cobalt(II)]

机译：聚[[μ-1,1'-（丁烷-1,4-二基）双（1H-苯并咪唑）-κ2N3：N3']的晶体结构{μ-4,4'-[1,4-亚苯基双（氧基）]二苯甲酸酯-κ4O，O'：O''，O''} ob钴（II）]

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In the title compound, [Co(C20H12O6)(C18H18N4)]n, the CoII atom, located on a twofold rotation axis, is hexacoordinated to four O from two bis-bidentate 4,4′-[phenylenebis(oxy)]dibenzoate (L) ligands and two N atoms from two 1,1′-(butane-1,4-diyl)bis(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N2O4 coordination environment. Polymeric zigzag chains along [102] are built up by the bridging L ligands. These chains are additionally connected by the bbbm ligands to produce a two-dimensional coordination polymer parallel too (010).

机译：在标题化合物[Co（C20H12O6）（C18H18N4）] n中，位于两倍旋转轴上的CoII原子从两个双双4,4'-[[亚苯基双（氧基）]二苯甲酸酯（ L）配体和来自两个1,1'-（1,1-丁烷-1,4-丁二基）双（1H-苯并咪唑）（bbbm）配体的两个N原子，形成扭曲的八面体顺式-N2O4配位环境。沿着[102]的聚合之字形链是由桥接的L配体建立的。这些链还通过bbbm配体连接，也产生了平行的二维配位聚合物（010）。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第6期|共页
作者
Xie C.; Zheng C.G.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTUREMETAL-ORGANIC FRAMEWORKSBIS-BENZIMIDAZOLEDICARBOXYLATE;

机译：晶体结构金属-有机框架SBIS-BENZIMIDAZOLED羧酸盐;

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1. Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O,O′:O′′,O′′′}cobalt(II)] [J] . Xie C., Zheng C.G. Acta Crystallographica Section E: Crystallographic Communications . 2015,第6期

机译：聚[[μ-1,1'-（丁烷-1,4-二基）双（1H-苯并咪唑）-κ2N3：N3']的晶体结构{μ-4,4'-[1,4-亚苯基双（氧基）]二苯甲酸酯-κ4O，O'：O''，O''} ob钴（II）]
2. [μ-1,1′-(Butane-1,4-diyl)di-1H-benzimidazole-κ2N3:N3′]bis{[N,N′-bis(carboxymethyl)ethylenediamine-N,N′-diacetato-κ5O,O′,O′′,N,N′]mercury(II)} methanol disolvate [J] . Li G.-S., Qian H.-Y., Xiao B., Acta Crystallographica Section E: Crystallographic Communications . 2009,第8期

机译：[μ-1,1'-（Butane-1,4-diyl）di-1H-benzimidazole-κ2N3：N3'] bis {[[N，N'-双（羧甲基）乙二胺-N，N'-二乙酸酯-κ5O ，O'，O''，N，N']汞（II）}溶解于甲醇
3. [μ-1,1′-(Butane-1,4-diyl)di-1H-benzimidazole-κ2N3:N3′]bis{[N,N′-bis(carboxymethyl)ethylenediamine-N,N′-diacetato-κ5O,O′,O′′,N,N′]mercury(II)} methanol disolvate [J] . Li G.-S., Qian H.-Y., Xiao B., Acta Crystallographica Section E: Crystallographic Communications . 2009,第8期

机译：[μ-1,1'-（Butane-1,4-diyl）di-1H-benzimidazole-κ2N3：N3'] bis {[[N，N'-双（羧甲基）乙二胺-N，N'-二乙酸酯-κ5O ，O'，O''，N，N']汞（II）}溶解于甲醇
4. Crystal structure of polyμ-11′-(butane-14-diyl)bis(1H-benzimidazole)-κ2N3:N3′{μ-44′-14-phenylenebis(oxy)dibenzoato-κ4OO′:O′′O′′′}cobalt(II) [O] . Chen Xie, ChangGe Zheng 2015

机译：聚μ-11-（butane-14-diyl）bis（1H-benzimidazole）-κ2的晶体结构ñ3：N3 {μ-44-14-亚苯基（氧基）二苯并-κ4OO：OO}钴（II）
5. catena-Poly[μ-aqua-2:1′κ2O:O-aqua-2κO-(2-fluorobenzoato-1κ2O,O′)(μ2-2-fluorobenzoato-2′:1κ2O:O′)bis(μ3-2-fluorobenzoato)-2′:1:2κ4O:O,O′:O′;1:2:1′κ5F,O:O,O′:O′-dilead(II)] [O] . Bi-Song Zhang 2008

机译：系列聚[＆＃956; -aqua-2：1＆＃8242;＆＃954; 20：O形aQUa-2＆＃954; O-（2- fluorobenzoato-1＆＃954; O，O＆＃8242）（＆＃956; 2-2-fluorobenzoato-2＆＃8242; 1＆＃954; 20：O＆＃8242;）双（＆＃956; 3-2-fluorobenzoato）-2＆＃8242; 1：2＆＃954; 40：O，O＆＃8242;：O＆＃8242 ;; 1：2：1＆＃8242;＆＃954; 5F，O：O，O＆＃8242;：O＆＃8242; -dilead（II）]

Crystal structure of poly[[μ-1,1′-(butane-1,4-di­yl)bis­(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenyl­enebis(­oxy)]di­ben­zo­ato-κ4O,O′:O′′,O′′′}cobalt(II)]

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Crystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2N3:N3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O,O′:O′′,O′′′}cobalt(II)]