Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate

Ikotun A.A.; Coogan M.P.; Owoseni A.A.; Bhuvanesh N.; Egharevba G.O.

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Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate

机译：四氟硼酸三羰基三（吡啶-κN）r（I）的晶体结构

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In the title compound, [Re(C6H5N)3(CO)3]BF4, the ReI ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π interactions, forming a three-dimensional framework. The F atoms of the BF4 anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11).

机译：在标题化合物[Re（C6H5N）3（CO）3] BF4中，ReI离子由三个吡啶N原子和三个羰基C原子配位。在每种情况下，羰基C原子反式为吡啶N原子。在晶体中，离子通过CHF氢键和CHHπ相互作用连接，形成三维框架。 BF4阴离子的F原子在两个位置无序排列，最终精制占有率为0.705（11）：0.295（11）。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第5期|共页
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Ikotun A.A.; Coogan M.P.; Owoseni A.A.; Bhuvanesh N.; Egharevba G.O.;
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中图分类晶体学;
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CRYSTAL STRUCTURERHENIUM(I) TRICARBONYL COMPLEXESTRICARBONYL TRIS-PYRIDYL RHENIUM(I) CATIONLUMINESCENT AGENT.;

机译：晶体结构HEN（I）三苯甲酰基络合三芳基三甲苯-吡啶基R（I）阳离子发光剂。;

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1. Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate [J] . Ikotun A.A., Coogan M.P., Owoseni A.A., Acta Crystallographica Section E: Crystallographic Communications . 2015,第5期

机译：四氟硼酸三羰基三（吡啶-κN）r（I）的晶体结构
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4. Structures of Borate Crystals Without Center of Inversion [C] . Anton S. Korotkov International Conference and Seminar on Micro/Nanotechnologies and Electron Devices . 2010

机译：无逆转中心的硼酸晶体结构
5. Hydrothermal chemistry, crystal structures, and spectroscopy of novel fluorides and borates. [D] . Underwood, Christopher Cole. 2013

机译：新型氟化物和硼酸盐的水热化学，晶体结构和光谱。
6. Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate [O] . Adebomi A. Ikotun, Micheal P. Coogan, Abimbola A. Owoseni, 2015

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Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate

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Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate